Day: November 3, 2021

Authors Lan, RC; Gao, YZ; Shen, C; Huang, R; Bao, JY; Zhang, ZP; Wang, Q; Zhang, LY; Yang, H in WILEY-V C H VERLAG GMBH published article about in [Lan, Ruochen; Shen, Chen; Bao, Jinying; Wang, Qian; Zhang, Lanying; Yang, Huai] Peking Univ, Coll Engn, Beijing Adv Innovat Ctr Mat Genome Engn, Beijing 100871, Peoples R China; [Lan, Ruochen; Shen, Chen; Bao, Jinying; Wang, Qian; Zhang, Lanying; Yang, Huai] Peking Univ, Coll Engn, Dept Mat Sci & Engn, Beijing 100871, Peoples R China; [Gao, Yanzi] Univ Sci & Technol Beijing, Inst Adv Mat & Technol, Beijing Adv Innovat Ctr Mat Genome Engn, Beijing 100083, Peoples R China; [Huang, Rui; Zhang, Zhongping] Univ Sci & Technol Beijing, Sch Mat Sci & Engn, Beijing 100083, Peoples R China; [Zhang, Lanying; Yang, Huai] Peking Univ, Minist Educ, Key Lab Polymer Chem & Phys, Beijing 100871, Peoples R China in 2021.0, Cited 32.0. Computed Properties of C13H10O. The Name is Benzophenone. Through research, I have a further understanding and discovery of 119-61-9

Imitating the structures and behaviors of natural creatures is of great significance to scientists to explore novel materials for practical applications. However, the design and fabrication of biomimetic devices with complex and outstanding performances is still on the way. A bilayer film composed of liquid crystalline networks (LCN) film and hydrochromic aggregation-induced-emission molecule-doped hydrophilic layer is prepared. Under different relative humidity, the composite film can deform and change fluorescence color simultaneously. The influence of the content of the hydrophilic matrix on the fluorescent property and humidity-responsive behaviors of the bilayer film is investigated. Thanks to the mechanical anisotropy provided by uniform-aligned LCN film, different modes of deformation of the bilayer film are achievable, like bending, curling, and twisting. More importantly, due to the independence of the LCN film and the non-mesogenic molecules brought by this bimorph strategy, complex alignment of the LCN film and modification by immiscible molecules are realized in a single LCN actuator. Based on the functional composite film, artificial flowers showing synergistic blooming and shape-changing is prepared. By regulating the molecular alignment of the LC mesogens of the LCN film, the artificial flowers can imitate various blooming behaviors of natural flowers like confederate jasmine and jade lotus.

Computed Properties of C13H10O. About Benzophenone, If you have any questions, you can contact Lan, RC; Gao, YZ; Shen, C; Huang, R; Bao, JY; Zhang, ZP; Wang, Q; Zhang, LY; Yang, H or concate me.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

An article Synthesis, Crystal Structure, and Agricultural Antimicrobial Evaluation of Novel Quinazoline Thioether Derivatives Incorporating the 1,2,4-Triazolo[4,3-a]pyridine Moiety WOS:000492802400006 published article about BIOLOGICAL EVALUATION; INSECTICIDAL ACTIVITY; FUNGICIDAL ACTIVITIES; DESIGN; ANTIFUNGAL; SERIES; ORYZAE; BASE in [Fan, Zhijiang; Shi, Jun; Luo, Na; Ding, Muhan; Bao, Xiaoping] Guizhou Univ, Ctr Res & Dev Fine Chem, State Key Lab Breeding Base Green Pesticide & Agr, Key Lab Green Pesticide & Agr Bioengn,Minist Educ, Guiyang 550025, Guizhou, Peoples R China in 2019, Cited 46. Recommanded Product: 88-68-6. The Name is 2-Aminobenzamide. Through research, I have a further understanding and discovery of 88-68-6

A total of 22 quinazoline thioether derivatives incorporating a 1,2,4-triazolo[4,3-a]pyridine moiety were designed, synthesized, and evaluated as antimicrobial agents in agriculture. Among these compounds, the chemical structure of compound 61 was further confirmed via single-crystal X-ray diffraction analysis. The bioassay results revealed that some of the compounds possessed noticeable in vitro antibacterial activities against the tested phytopathogenic bacteria. For example, compounds 6b and 6g had EC50 values as low as 10.0 and 24.7 mu g/mL against Xanthomonas axonopodis pv. citri (Xac), respectively, which were significantly better than that of the commercial agrobactericide bismerthiazol (56.9 mu g/mL). Particularly, compound 6b was also found to be capable of suppressing the pathogenic bacterium Xanthomonas oryzae pv. oryzae (Xoo) approximately 12-fold more potent than control bismerthiazol, in terms of their EC 50 values (7.2 versus 89.8 mu g/mL). Importantly, the most active compound 6b turned out to be one with the highest hydrophilicity and the lowest molecular weight within the series. In vivo bioassays further showed the application prospect of 6b as a promising plant bactericide for controlling Xoo. Additionally, in vitro antifungal activities of these compounds were also evaluated at the concentration of 50 mu g/mL. Overall, the present study demonstrated the potential of 1,2,4-triazolo[4,3-a]pyridine-bearing quinazoline thioether derivatives as efficient agricultural antibacterial agents for crop protection.

About 2-Aminobenzamide, If you have any questions, you can contact Fan, ZJ; Shi, J; Luo, N; Ding, MH; Bao, XP or concate me.. Recommanded Product: 88-68-6

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Recently I am researching about STRUCTURAL-CHARACTERIZATION; CATALYTIC-HYDROGENATION; CARBON-DIOXIDE; BORANE; COMPLEXES; METAL; NMR; DERIVATIVES; REDUCTION; LIGANDS, Saw an article supported by the CNRSCentre National de la Recherche Scientifique (CNRS)European Commission; CEFIPRA [5905-1]; Service de Spectrometrie de Masse”, Universite de Toulouse [ICT-FR2599]. Formula: C13H10O. Published in ROYAL SOC CHEMISTRY in CAMBRIDGE ,Authors: Ayyappan, R; Coppel, Y; Vendier, L; Ghosh, S; Sabo-Etienne, S; Bontemps, S. The CAS is 119-61-9. Through research, I have a further understanding and discovery of Benzophenone

Four lithium phosphine borohydride compounds featuring phenyl and naphthyl linkers have been synthesized. In-depth NMR analysis affords evidence for non-bonded through space P-B coupling. Reactivity towards CO2 leads to LiH transfer and to the quantitative formation of the corresponding ambiphilic phosphine-borane products.

About Benzophenone, If you have any questions, you can contact Ayyappan, R; Coppel, Y; Vendier, L; Ghosh, S; Sabo-Etienne, S; Bontemps, S or concate me.. Formula: C13H10O

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Application In Synthesis of 1-Phenylurea. I found the field of Chemistry; Science & Technology – Other Topics; Engineering very interesting. Saw the article Enhanced Surface Area, Graphene Quantum Dots, and Functional Groups for the Simple Acid-Treated Carbon Fiber Electrode of Flexible Fiber-Type Solid-State Supercapacitors without Active Materials published in 2020.0, Reprint Addresses Lin, LY (corresponding author), Natl Taipei Univ Technol, Dept Chem Engn & Biotechnol, Taipei 10608, Taiwan.; Lin, LY (corresponding author), Res Ctr Energy Conservat New Generat Residential, Taipei 10608, Taiwan.. The CAS is 64-10-8. Through research, I have a further understanding and discovery of 1-Phenylurea.

Flexible fiber-type solid-state supercapacitors (FSCs) are demanded for energy storage of wearable soft electronics. A flexible carbon fiber (CF) with high electrical conductivity and good energy storage ability can act as the current collector and the active material simultaneously. Improving the energy storage ability of the CF without depositing active materials is highly promising to avoid active materials from peeling off, especially under bending conditions. In this study, the CF is treated with acid mixtures containing different HNO3 to H2SO4 ratios. The roughened surface and the production of graphene quantum dots and functional groups are achieved for the acid-treated CF, especially for the CF treated with the acid mixtures. The largely enhanced specific capacitance (C-L) is first obtained for the optimized CF electrode (641.08 mF/cm at 5 mV/s) treated with the acid mixture containing the HNO3 to H2SO4 ratio of 1 to 3. The FSC also shows a maximum energy density of 16.57 mu W h/cm at the power density of 62.50 mu W/cm, as well as a C-L retention of 77% and Coulombic efficiency of 100% in 5000 times of a charge/discharge cycling process. Excellent flexibility is also attained for the FSC with no shape distortion of cyclic voltammetry curves measured under the bending angle of 180 degrees and with 1000 times of repeated bending. This work proposes a simple acid treatment to largely enhance the energy storage ability of pure CF electrodes. The bifunctional substance with current collecting and energy storing abilities is expected to be well developed in the future for applying on numerous efficient flexible energy storage devices.

Application In Synthesis of 1-Phenylurea. About 1-Phenylurea, If you have any questions, you can contact Hsiao, YJ; Lin, LY or concate me.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

In 2020 BIOORG MED CHEM LETT published article about POTENTIAL AGENTS; MEMORY; PHOSPHODIESTERASES; DYSFUNCTION in [Huang, Xian-Feng; Dong, Yan-Hua; Ke, Heng-Ming; Song, Guo-Qiang; Xu, De-Feng] Changzhou Univ, Sch Pharmaceut Engn & Life Sci, Changzhou 213164, Jiangsu, Peoples R China; [Huang, Xian-Feng; Dong, Yan-Hua; Ke, Heng-Ming; Song, Guo-Qiang; Xu, De-Feng] Changzhou Univ, Adv Catalysis Green Mfg Collaborat Innovat Ctr, Changzhou 213164, Jiangsu, Peoples R China; [Wang, Jin-Hui] Wenzhou Med Univ, Wenzhou 3 Clin Inst, Wenzhou Peoples Hosp, Wenzhou 325000, Zhejiang, Peoples R China in 2020, Cited 28. The Name is 2-Aminobenzamide. Through research, I have a further understanding and discovery of 88-68-6. Recommanded Product: 2-Aminobenzamide

A series of novel rutaecarpine derivatives were synthesized and subjected to pharmacological evaluation as PDE5 inhibitors. The structure-activity relationships were discussed and their binding conformation and simultaneous interaction mode were further clarified by the molecular docking studies. Among the 25 analogues, compound 8i exhibited most potent PDE5 inhibition with IC50 values about 0.086 mu M. Moreover, it also produced good effects against scopolamine-induced cognitive impairment in vivo. These results might bring significant instruction for further development of potential PDE5 inhibitors derived from rutaecarpine as a good candidate drug for the treatment of Alzheimer’s disease.

About 2-Aminobenzamide, If you have any questions, you can contact Huang, XF; Dong, YH; Wang, JH; Ke, HM; Song, GQ; Xu, DF or concate me.. Recommanded Product: 2-Aminobenzamide

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Authors Romero, IA; van Dillewijn, P; Nesme, J; Sorensen, SJ; Romero, E in ELSEVIER published article about BIOREMEDIATION SYSTEMS; BACTERIAL COMMUNITY; INCP-1 PLASMIDS; DEGRADATION; DIURON; SOIL; BIODEGRADATION; MINERALIZATION; HYDROLASE; IMPACTS in [Aguilar Romero, Ines; van Dillewijn, Pieter; Romero, Esperanza] CSIC, EEZ, Dept Environm Protect, C Prof Albareda 1, E-18008 Granada, Spain; [Nesme, Joseph; Sorensen, Soren J.] Univ Copenhagen, Dept Biol, Sect Microbiol, DK-2100 Copenhagen, Denmark in 2019.0, Cited 44.0. SDS of cas: 64-10-8. The Name is 1-Phenylurea. Through research, I have a further understanding and discovery of 64-10-8

Despite certain limitations, bioaugmentation enhances the efficiency of bioremediation systems. In this study, three aqueous extracts (APE, ACE and APE) from aged residual biomixtures in three biopurification systems (BPSs) exposed to pesticides at a pilot scale were found to improve pesticide removal. The addition of ACEs and AVEs to solutions containing the model compound diuron increased removal rates 6- and 17-fold, respectively, as compared to APEs. These extracts also increased the removal of the metabolite 3,4-dichloroaniline, while AVEs, in particular, were found to remove all pesticides within 9 days. Three metabolites less hazardous than 3,4-dichloroaniline were identified by SPME/GC/MS. AVEs, which also enhance linuron removal in liquid media, were found to increase diuron removal 6-fold in BPSs. We observed an increase in the relative abundance of taxa, such as Chloroflexi, Acidobacteria, Gemmatimonadetes, Firmicutes, Deinococcus-Thermus and especially Proteobacteria (10%), in AV biomixtures, as well as an enrichment of gamma-proteobacteria and the actinobacterial genus Dokdonella in AVEs with respect to initial noncontaminated IV biomixture. We demonstrate that extracts containing a pollutant-acclimatized microbiome could be used as part of a bioaugmentation strategy to improve the functioning of on-farm BPSs and contaminated systems. (c) 2019 Elsevier B.V. All rights reserved.

SDS of cas: 64-10-8. About 1-Phenylurea, If you have any questions, you can contact Romero, IA; van Dillewijn, P; Nesme, J; Sorensen, SJ; Romero, E or concate me.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Category: thiomorpholine. Authors Fernandez-Lobato, L; Lopez-Sanchez, Y; Blejman, G; Jurado, F; Moyano-Fuentes, J; Vera, D in ELSEVIER SCI LTD published article about in [Fernandez-Lobato, L.; Jurado, F.; Vera, D.] Univ Jaen, Escuela Politecn Super, Dept Elect Engn, Linares 23700, Spain; [Lopez-Sanchez, Y.] Univ Jaen, Dept Econ, Lab Anal & Innovat Tourism LAInnTUR, Jaen, Spain; [Blejman, G.] Circular Carbon GmbH, Madrid, Spain; [Moyano-Fuentes, J.] Univ Jaen, Escuela Politecn Super, Dept Business Org Mkt & Sociol, Linares 23700, Spain in 2021.0, Cited 57.0. The Name is 1-Phenylurea. Through research, I have a further understanding and discovery of 64-10-8

Spain is the first olive oil producer worldwide (representing around 45%), with more than 80% of its agricultural area dedicated to this crop. The goal of this study is to assess the environmental impact of the Spanish virgin olive oil production, attending to the farming and industrial phases. A Life Cycle Assessment (LCA) is conducted for 5 harvests in approximately 4.000 ha of olive grove in Jaen, the largest producer region of Spain. The type of farming is the most representative in Spain: conventional (non-organic), with a medium-low slope, extensive (100-150 trees per ha) and around 60% dryland orchards. The industrial phase is based on 2-phase extraction process and olive pomace valorization. The functional unit (FU) chosen for the comparative analysis is 1 kg of unpacked virgin olive oil under a perspective from cradle to gate. One of the most representative categories, climate change, places the average environmental impact in 2.43 kg CO2 eq/kg, while the range is between 1.93 and 3.00 kg CO2 eq/kg depending on the harvest. Huge differences between values are observed in the farming phase and they are mostly caused by the virgin olive oil yield of every harvest. The carbon sequestration analyses and the impact produced per FU ranges from 43.78% (for 15/16 harvest) to 46.36% (for 17/18). The impact hotspots detected in the farming phase, in terms of climate change potential, are the categories of plant protection products and herbicides (24.11% of the average value) and fertilizers (20.01%). However, the environmental impact of the industrial phase is relatively constant, with a value of 0.547-0.554 kg of CO2 equivalent. The 80.74% is caused by pomace valorization, which translated to the average whole value, represents the 18.56%. (C) 2020 Elsevier Ltd. All rights reserved.

Category: thiomorpholine. About 1-Phenylurea, If you have any questions, you can contact Fernandez-Lobato, L; Lopez-Sanchez, Y; Blejman, G; Jurado, F; Moyano-Fuentes, J; Vera, D or concate me.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

In 2021 SOL RRL published article about POLYMER SOLAR-CELLS; SMALL-MOLECULE ACCEPTOR; NON-FULLERENE; CHARGE-TRANSFER; ELECTRON-ACCEPTOR; THEORETICAL DESIGN; ENERGY-LEVELS; PERFORMANCE; EFFICIENCY; DERIVATIVES in [Sui, Ming-Yue; Li, Ming-Yang; Ren, Yue; Sun, Guang-Yan] Yanbian Univ, Fac Sci, Dept Chem, Yanji 133002, Jilin, Peoples R China; [Sun, Guang-Yan] Jilin Univ, Zhuhai Coll, Fac Chem Engn & New Energy Mat, Zhuhai 519041, Guangdong, Peoples R China in 2021, Cited 86. The Name is Anthrone. Through research, I have a further understanding and discovery of 90-44-8. Name: Anthrone

The ring-expanded strategy in nonfullerene acceptors (NFAs) with the acceptor-donor-acceptor backbone has been reported to be an effective method to improve the fill factor (FF), open circuit voltage (VOC), and short circuit current (JSC) simultaneously in organic photovoltaics. However, design control is still missing in the ring-expanded strategy, and is urgently needed to further develop the origins and rules. To give insight into this strategy, a detailed theoretical study of the ring-expanded mechanism is performed on the systems comprising different 9,9 ‘-bifluorenylidene-based cores and 1,1-dicyanomethylene-3-indanone group. Some main parameters involved in photoelectric conversion mechanism under the donor excitation (DE) and/or acceptor excitation (AE) are assessed by changing the position and size of ring-expanded modes. The results show that the external ring-expanded modes can not only maintain the original advantage as much as possible, variations in sizes and positions also offer them an opportunity to regulate the aforementioned parameters systematically, leading to better improvement regardless of AE or DE. Thus, the steady improvement in performance mentioned previously is the key to overcoming the negative correlation among FF, VOC, and JSC. This insight and discovery of the ring-expanded strategy provides new design approaches for the next generation of NFAs.

About Anthrone, If you have any questions, you can contact Sui, MY; Li, MY; Ren, Y; Sun, GY or concate me.. Name: Anthrone

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

An article A Fast and General Route to Ketones from Amides and Organolithium Compounds under Aerobic Conditions: Synthetic and Mechanistic Aspects WOS:000607583600001 published article about BASIS-SETS; ORGANOMETALLIC REAGENTS; ACYLATION; ALDEHYDES; SECONDARY; TERTIARY; ELEMENTS; AMINES; ATOMS; ALKYL in [Ghinato, Simone; Territo, Davide; Maranzana, Andrea; Blangetti, Marco; Prandi, Cristina] Univ Torino, Dipartimento Chim, Via P Giuria 7, I-10125 Turin, Italy; [Capriati, Vito] Univ Bari Aldo Moro, Consorzio CINMPIS, Dipartimento Farm Sci Farmaco, Via E Orabona 4, I-70125 Bari, Italy in 2021.0, Cited 56.0. The Name is Benzophenone. Through research, I have a further understanding and discovery of 119-61-9. Category: thiomorpholine

We report that the nucleophilic acyl substitution reaction of aliphatic and (hetero)aromatic amides by organolithium reagents proceeds quickly (20 s reaction time), efficiently, and chemoselectively with a broad substrate scope in the environmentally responsible cyclopentyl methyl ether, at ambient temperature and under air, to provide ketones in up to 93 % yield with an effective suppression of the notorious over-addition reaction. Detailed DFT calculations and NMR investigations support the experimental results. The described methodology was proven to be amenable to scale-up and recyclability protocols. Contrasting classical procedures carried out under inert atmospheres, this work lays the foundation for a profound paradigm shift of the reactivity of carboxylic acid amides with organolithiums, with ketones being straightforwardly obtained by simply combining the reagents under aerobic conditions and with no need of using previously modified or pre-activated amides, as recommended.

Category: thiomorpholine. About Benzophenone, If you have any questions, you can contact Ghinato, S; Territo, D; Maranzana, A; Capriati, V; Blangetti, M; Prandi, C or concate me.

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem

Recommanded Product: 99-61-6. Recently I am researching about FORMAL TOTAL-SYNTHESIS; GRAM-SCALE SYNTHESIS; F METHYL-ESTER; ALKYNE METATHESIS; OXIDATIVE CYCLIZATION; BIOLOGICAL EVALUATION; ACID CATALYST; GOLD; PLATINUM; POLYKETIDE, Saw an article supported by the Swiss National Science FoundationSwiss National Science Foundation (SNSF)European Commission; Alexander-von-Humboldt FoundationAlexander von Humboldt Foundation; MPGMax Planck Society; Projekt DEAL. Published in WILEY-V C H VERLAG GMBH in WEINHEIM ,Authors: Schulthoff, S; Hamilton, JY; Heinrich, M; Kwon, Y; Wirtz, C; Furstner, A. The CAS is 99-61-6. Through research, I have a further understanding and discovery of 3-Nitrobenzaldehyde

Total synthesis allowed the constitution of the cytotoxic marine macrolides of the formosalide family to be confirmed and their previously unknown stereostructure to be assigned with confidence. The underlying blueprint was inherently modular to ensure that each conceivable isomer could be reached. This flexibility derived from the use of strictly catalyst controlled transformations to set the stereocenters, except for the anomeric position, which is under thermodynamic control; as an extra safety measure, all stereogenic centers were set prior to ring closure to preclude any interference of the conformation adopted by the macrolactone rings of the different diastereomers. Late-stage macrocyclization by ring-closing alkyne metathesis was followed by a platinum-catalyzed transannular 6-exo-dig hydroalkoxylation/ketalization to craft the polycyclic frame. The side chain featuring a very labile unsaturation pattern was finally attached to the core by Stille coupling.

About 3-Nitrobenzaldehyde, If you have any questions, you can contact Schulthoff, S; Hamilton, JY; Heinrich, M; Kwon, Y; Wirtz, C; Furstner, A or concate me.. Recommanded Product: 99-61-6

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem