Fujihira, Y; Hirano, K; Ono, M; Mimura, H; Kagawa, T; Sedgwick, DM; Fustero, S; Shibata, N in [Fujihira, Yamato; Ono, Makoto; Shibata, Norio] Nagoya Inst Technol, Dept Life Sci & Appl Chem, Nagoya, Aichi 4668555, Japan; [Hirano, Kazuki; Shibata, Norio] Nagoya Inst Technol, Dept Nanopharmaceut Sci, Nagoya, Aichi 4668555, Japan; [Mimura, Hideyuki; Kagawa, Takumi] Tosoh Finechem Corp, Shunan 7460006, Japan; [Sedgwick, Daniel M.; Fustero, Santos] Univ Valencia, Dept Quim Organ, Burjassot 46100, Spain; [Shibata, Norio] Zhejiang Normal Univ, Inst Adv Fluorine Containing Mat, Jinhua 321004, Zhejiang, Peoples R China published Pentafluoroethylation of Carbonyl Compounds by HFC-125 via the Encapsulation of the K Cation with Glymes in 2021, Cited 53. Category: thiomorpholine. The Name is Benzophenone. Through research, I have a further understanding and discovery of 119-61-9.
A simple protocol to overcome the explosive pentafluoroethylation of carbonyl compounds by HFC-125 is described. The use of potassium (K) bases with triglyme or tetraglyme as a solvent safely yields the pentafluoroethylation products in good to high yields. The experimental results suggest that an encapsulation of the K cation by glymes as K(glyme)(2) inhibits the contact between the K cation and the reactive anionic pentafluoroethyl counterion, preventing their transformation into KF and explosive tetrafluoroethylene (TFE). The generation of sterically demanding [K(G3)(2)](+) and [K(G4)(2)](+) is an effective way as an unstable pentafluoroethyl anion reservoir.
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Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem