In 2020 J AM CHEM SOC published article about METAL-OXO; NONHEME; REACTIVITY; OXIDATION; DIOXYGEN; INTERMEDIATE; AUTOXIDATION; H2O2 in [Kass, Dustin; Corona, Teresa; Warm, Katrin; Braun-Cula, Beatrice; Ray, Kallol] Humboldt Univ, Inst Chem, D-12489 Berlin, Germany; [Kuhlmann, Uwe; Hildebrandt, Peter] Tech Univ Berlin, Dept Chem, D-10623 Berlin, Germany; [Bill, Eckhard] Max Planck Inst Chem Energiekonvers, D-45470 Mulheim, Germany; [Mebs, Stefan; Dau, Holger; Haumann, Michael] Free Univ Berlin, Dept Phys, D-14195 Berlin, Germany; [Swart, Marcel] ICREA, Barcelona 08010, Spain; [Swart, Marcel] Univ Girona, IQCC, Girona 17003, Spain in 2020, Cited 38. The Name is Anthrone. Through research, I have a further understanding and discovery of 90-44-8. HPLC of Formula: C14H10O
In soluble methane monooxygenase enzymes (sMMO), dioxygen (O-2) is activated at a diiron(II) center to form an oxodiiron(IV) intermediate Q that performs the challenging oxidation of methane to methanol. An analogous mechanism of O-2 activation at mono- or dinuclear iron centers is rare in the synthetic chemistry. Herein, we report a mononuclear non-heme iron(II)cyclam complex, 1-trans, that activates O-2 to form the corresponding iron(IV)-oxo complex, 2-trans, via a mechanism reminiscent of the O-2 activation process in sMMO. The conversion of 1-trans to 2-trans proceeds via the intermediate formation of an iron(III)-superoxide species 3, which could be trapped and spectroscopically characterized at -50 degrees C. Surprisingly, 3 is a stronger oxygen atom transfer (OAT) agent than 2-trans; 3 performs OAT to 1-trans or PPh 3 to yield 2-trans quantitatively. Furthermore, 2-trans oxidizes the aromatic C-H bonds of 2,6-di-tert-butylphenol, which, together with the strong OAT ability of 3, represents new domains of oxoiron(IV) and superoxoiron(III) reactivities.
Welcome to talk about 90-44-8, If you have any questions, you can contact Kass, D; Corona, T; Warm, K; Braun-Cula, B; Kuhlmann, U; Bill, E; Mebs, S; Swart, M; Dau, H; Haumann, M; Hildebrandt, P; Ray, K or send Email.. HPLC of Formula: C14H10O
Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem