Authors Patra, T; Das, M; Daniliuc, CG; Glorius, F in NATURE RESEARCH published article about SHARPLESS ASYMMETRIC AMINOHYDROXYLATION; OLEFIN COUPLING REACTIONS; CENTERED RADICALS; NITROGEN; ALCOHOLS; OXYAMINATION; DERIVATIVES; CYCLIZATION; PRECURSORS; CONVERSION in [Patra, Tuhin; Das, Mowpriya; Daniliuc, Constantin G.; Glorius, Frank] Westfalische Wilhelms Univ Munster, Organ Chem Inst, Munster, Germany in 2021.0, Cited 60.0. Product Details of 119-61-9. The Name is Benzophenone. Through research, I have a further understanding and discovery of 119-61-9
The 1,2-aminoalcohol motif is one of the most prevalent structural components found in high-value organic molecules, including pharmaceuticals and natural products. Generally, its preparation requires pre-functionalized substrates and manipulations of one functional group at a time to achieve the desired regioisomer. Herein, we describe a metal-free photosensitization protocol for the installation of both amine and alcohol functionalities into alkene feedstocks in a single step. This approach is enabled by the identification of oxime carbonate as a suitable bifunctional source of both oxygen- and nitrogen-centred radicals for addition across alkenes with complementary regioselectivity compared to Sharpless aminohydroxylation. Use of orthogonal protection for amine and alcohol functionalities enables the direct synthetic diversification of one functional handle without influencing the other. With the use of readily available starting materials, convergent synthesis and mild reaction conditions, this process is well suited for use in various synthetic endeavours.
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Reference:
Thiomorpholine – Wikipedia,
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