An article Sustainable methine sources for the synthesis of heterocycles under metal- and peroxide-free conditions WOS:000461723200006 published article about C-H BOND; CARBON-MONOXIDE SOURCE; CATALYZED SYNTHESIS; DIMETHYL-SULFOXIDE; ALPHA-METHYLATION; FACILE SYNTHESIS; GREEN CHEMISTRY; TERTIARY-AMINES; SITU GENERATION; BUILDING-BLOCK in [Senadi, Gopal Chandru; Kudale, Vishal Suresh; Wang, Jeh-Jeng] Kaohsiung Med Univ, Dept Med & Appl Chem, 100,Shiquan 1st Rd, Kaohsiung 807, Taiwan; [Wang, Jeh-Jeng] Kaohsiung Med Univ Hosp, Dept Med Res, 100,Tzyou 1st Rd, Kaohsiung 807, Taiwan; [Senadi, Gopal Chandru] SRM Inst Sci & Technol, Dept Chem, Chennai 603203, Tamil Nadu, India in 2019, Cited 132. The Name is 2-Aminobenzamide. Through research, I have a further understanding and discovery of 88-68-6. Product Details of 88-68-6
Alcohols and ethers were identified as sustainable methine sources for synthesizing quinazolinone and benzimidazole derivatives using a combination of TsOHH2O/O-2 and appropriate bis-nucleophiles for the first time. Deuterium labeling studies clearly proved that the C-2 hydrogen of the synthesized heterocycles came from the methine source. These unique reaction conditions were successfully applied to the synthesis of echinozolinone (2e), 2f (a common precursor of rutaecarpine and (+/-) evodiamine), and dimedazole (6d). Notable features of this method include its low toxicity, use of commercial feedstocks as substrates, low cost, broad functional group tolerance and suitability for a wide range of bis-nucleophilic starting materials.
Product Details of 88-68-6. Welcome to talk about 88-68-6, If you have any questions, you can contact Senadi, GC; Kudale, VS; Wang, JJ or send Email.
Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem