Application In Synthesis of Benzophenone. In 2021.0 REACT FUNCT POLYM published article about PHOTOPOLYMERIZATION; MIGRATION; EMULSION; COATINGS; BEHAVIOR in [Huo, S.; Zhou, H. Y.; Wang, J. X.] Hebei Univ Technol, Sch Chem Engn & Technol, 8 Guang Rong Dao, Tianjin 300130, Peoples R China; [Wang, J. X.] Hebei Univ Technol, Hebei Prov Key Lab Green Chem Technol & High Effi, Tianjin 300130, Peoples R China in 2021.0, Cited 39.0. The Name is Benzophenone. Through research, I have a further understanding and discovery of 119-61-9.
A novel emulsified photoinitiator (named as OP10-IPDI-2959) was prepared by the reaction of isophorone diisocyanate (IPDI) with 2-hydroxy-4?-(2-hydroxyethoxy)-2-methylpropiophenone (Ir-2959) and nonylphenol polyoxyethylene ether (OP-10). The structure of OP10-IPDI-2959 was characterized by FT-IR, 1H NMR, UV?vis and high-resolution mass spectrometry. The photochemical behavior of OP10-IPDI-2959 was investigated through the photolysis and polymerization of neopentyl glycol diacrylate (NPGDA), mixture of epoxy acrylate resin and 1,6-hexanediol diacrylate (HDDA). Under irradiation of UV light, the OP10-IPDI-2959 has similar photochemical properties with the Ir-2959. Combined with benzophenone, the photoinitiated rate of OP10-IPDI-2959 is higher than that of Ir-2959. The polyoxyethylene fragment of OP10-IPDI-2959 is not only an alternative to toxic amine as hydrogen donor, but also a hydrophilic unit for interface between oil and water. The OP10-IPDI-2959 can effectively emulsify the epoxy acrylate resin and 1,6-hexanediol diacrylate mixture to form low viscosity emulsion. Compared with Ir-2959, OP10-IPDI-2959 has good photoinitiation activity, lower migration and good water emulsification performance.
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Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem