I found the field of Chemistry very interesting. Saw the article Palladium-Catalyzed Allyl-Allyl Reductive Coupling of Allylamines or Allylic Alcohols with H-2 as Sole Reductant published in 2021.0. Category: thiomorpholine, Reprint Addresses Huang, HM (corresponding author), Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Hefei 230026, Peoples R China.; Huang, HM (corresponding author), Univ Sci & Technol China, Dept Chem, Hefei 230026, Peoples R China.; Huang, HM (corresponding author), Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China.; Huang, HM (corresponding author), Chinese Acad Sci, Ctr Excellence Mol Synth, Hefei 230026, Peoples R China.. The CAS is 119-61-9. Through research, I have a further understanding and discovery of Benzophenone
Catalytic carbon-carbon bond formation building on reductive coupling is a powerful method for the preparation of organic compounds. The identification of environmentally benign reductants is key for establishing an efficient reductive coupling reaction. Herein an efficient strategy enabling H-2 as the sole reductant for the palladium-catalyzed allyl-allyl reductive coupling reaction is described. A wide range of allylamines and allylic alcohols as well as allylic ethers proceed smoothly to deliver the C-C coupling products under 1 atm of H-2. Kinetic studies suggested that the dinuclear palladium species was involved in the catalytic cycle.
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Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem