Iwata, T; Hyodo, M; Fukami, T; Shiota, Y; Yoshizawa, K; Shindo, M in [Iwata, Takayuki; Shiota, Yoshihito; Yoshizawa, Kazunari; Shindo, Mitsuru] Kyushu Univ, Inst Mat Chem & Engn, Kasuga, Fukuoka 8168580, Japan; [Hyodo, Mizuki; Fukami, Takuto] Kyushu Univ, Interdisciplinary Grad Sch Engn Sci, Kasuga, Fukuoka 8168580, Japan published Anthranoxides as Highly Reactive Arynophiles for the Synthesis of Triptycenes in 2020, Cited 62. Recommanded Product: 90-44-8. The Name is Anthrone. Through research, I have a further understanding and discovery of 90-44-8.
We report herein an efficient method to synthesize triptycenes by the reaction of benzynes and anthranoxides, which are electron-rich and readily prepared from the corresponding anthrones. Using this method, 1,9-syn-substituted triptycenes were regioselectively obtained employing 3-methoxybenzynes. This method was also applied to synthesize pentiptycenes. A DFT study revealed that the cycloaddition of lithium anthranoxide and benzyne proceeds stepwise.
Recommanded Product: 90-44-8. Welcome to talk about 90-44-8, If you have any questions, you can contact Iwata, T; Hyodo, M; Fukami, T; Shiota, Y; Yoshizawa, K; Shindo, M or send Email.
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