An article Cobalt single atom site catalysts with ultrahigh metal loading for enhanced aerobic oxidation of ethylbenzene WOS:000604828900002 published article about OXYGEN REDUCTION; SELECTIVE OXIDATION; ELECTRONIC-STRUCTURE; DOPED GRAPHENE; CARBON; EFFICIENT; NANOPARTICLES; ACETOPHENONE; INSIGHT in [Xiong, Yu] Cent South Univ, Dept Chem & Chem Engn, Changsha 410083, Peoples R China; [Xiong, Yu; Xin, Pingyu; Zhang, Jian; Wang, Dingsheng; Li, Yadong] Tsinghua Univ, Dept Chem, Beijing 100084, Peoples R China; [Sun, Wenming] China Agr Univ, China Coll Sci, Beijing 100193, Peoples R China; [Han, Yunhu] Northwestern Polytech Univ, Inst Flexible Elect, Xian 710072, Peoples R China; [Zheng, Xusheng; Yan, Wensheng] Univ Sci & Technol China, Natl Synchrotron Radiat Lab, Hefei 230029, Peoples R China; [Dong, Juncai] Chinese Acad Sci, Inst High Energy Phys, Beijing Synchrotron Radiat Facil, Beijing 100084, Peoples R China in 2021.0, Cited 57.0. The Name is Benzophenone. Through research, I have a further understanding and discovery of 119-61-9. Application In Synthesis of Benzophenone
The oxidation of hydrocarbons to produce high value-added compounds (ketones or alcohols) using oxygen in air as the only oxidant is an efficient synthetic strategy from both environmental and economic views. Herein, we successfully synthesized cobalt single atom site catalysts (Co SACs) with high metal loading of 23.58 wt.% supported on carbon nitride (CN), which showed excellent catalytic properties for oxidation of ethylbenzene in air. Moreover, Co SACs show a much higher turn-over frequency (19.6 h(-1)) than other reported non-noble catalysts under the same condition. Comparatively, the as-obtained nanosized or homogenous Co catalysts are inert to this reaction. Co SACs also exhibit high selectivity (97%) and stability (unchanged after five runs) in this reaction. DFT calculations reveal that Co SACs show a low energy barrier in the first elementary step and a high resistance to water, which result in the robust catalytic performance for this reaction.
About Benzophenone, If you have any questions, you can contact Xiong, Y; Sun, WM; Han, YH; Xin, PY; Zheng, XS; Yan, WS; Dong, JC; Zhang, J; Wang, DS; Li, YD or concate me.. Application In Synthesis of Benzophenone
Reference:
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