Authors Yu, Y; Li, XT; Yuan, YJ; Zhang, HL in ELSEVIER SCI LTD published article about in [Yu, Yan; Li, Xitian; Yuan, Yongjie; Zhang, Hailiang] Xiangtan Univ, Key Lab Adv Funct Polymer Mat Coll & Univ Hunan P, Key Lab Polymer Mat & Applicat Technol Hunan Prov, Coll Chem, Xiangtan 411105, Hunan, Peoples R China in 2021.0, Cited 42.0. Recommanded Product: Benzophenone. The Name is Benzophenone. Through research, I have a further understanding and discovery of 119-61-9
Fluorescent materials with a large enough Stokes shift (>100 nm) have widely prospect in light conversion agricultural film, cell-imaging, chemosensory and so on. However, most of traditional fluorescent dyes displayed small Stokes shifts which severely limited their application. In this paper, a side-chain alternative copolymer named P(DMPNI-alt-TPE) was developed, in which the two fluorophores were next to each other: the AIE-active tetraphenylethene (TPE) acted as energy donor, while naphthalimide derivative (DMPNI) with intramolecular charge transfer (ICT) character as energy acceptor. Attributed to this unique structure, the copolymer combined efficient dark/fluorescence resonance energy transfer (DRET/FRET) and polarity-sensitivity. And therefore it showed impressive large pseudo-Stokes Shift up to 304 nm and 302 nm in solution and aggregative state respectively. Interestingly, this copolymer exhibited a V-shaped fluorescence variation curve in a series of THF solutions with increasing fraction of water. Moreover, P(DMPNI-alt-TPE) emitted different color fluorescence in various solvents upon UV light, so that its pseudo-Stokes shift was not only large but also tunable, and the changing range was from 262 to 304 nm. Lastly, the potential possibility of P(DMPNI-alt-TPE) as light conversion agricultural film was investigated. This research provided a new approach for the development of fluorescence materials with large and tunable Stokes shift.
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Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem