In 2021.0 J AM CHEM SOC published article about O BOND ACTIVATION; MOLECULAR-OXYGEN; SELECTIVE OXIDATION; SINGLET OXYGEN; C=C BONDS; COMPLEX; DIOXYGEN; OLEFINS; REACTIVITY; IRON in [Huang, Zhiliang; Guan, Renpeng; Bennett, Elliot L.; Robertson, Craig M.; Xiao, Jianliang] Univ Liverpool, Dept Chem, Liverpool L69 7ZD, Merseyside, England; [Shanmugam, Muralidharan; Brookfield, Adam; McInnes, Eric J. L.] Univ Manchester, Dept Chem, Manchester M13 9PL, Lancs, England; [Shanmugam, Muralidharan; Brookfield, Adam; McInnes, Eric J. L.] Univ Manchester, Photon Sci Inst, Manchester M13 9PL, Lancs, England in 2021.0, Cited 58.0. The Name is Benzophenone. Through research, I have a further understanding and discovery of 119-61-9. SDS of cas: 119-61-9
The oxidative cleavage of C = C double bonds with molecular oxygen to produce carbonyl compounds is an important transformation in chemical and pharmaceutical synthesis. In nature, enzymes containing the first-row transition metals, particularly heme and non-heme iron-dependent enzymes, readily activate O-2 and oxidatively cleave C = C bonds with exquisite precision under ambient conditions. The reaction remains challenging for synthetic chemists, however. There are only a small number of known synthetic metal catalysts that allow for the oxidative cleavage of alkenes at an atmospheric pressure of O-2, with very few known to catalyze the cleavage of nonactivated alkenes. In this work, we describe a light-driven, Mn-catalyzed protocol for the selective oxidation of alkenes to carbonyls under 1 atm of O-2. For the first time, aromatic as well as various nonactivated aliphatic alkenes could be oxidized to afford ketones and aldehydes under clean, mild conditions with a first row, biorelevant metal catalyst. Moreover, the protocol shows a very good functional group tolerance. Mechanistic investigation suggests that Mn-oxo species, including an asymmetric, mixed-valent bis(mu-oxo)-Mn(III,IV) complex, are involved in the oxidation, and the solvent methanol participates in O-2 activation that leads to the formation of the oxo species.
SDS of cas: 119-61-9. About Benzophenone, If you have any questions, you can contact Huang, ZL; Guan, RP; Shanmugam, M; Bennett, EL; Robertson, CM; Brookfield, A; McInnes, EJL; Xiao, JL or concate me.
Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem