Application In Synthesis of Benzophenone. Hutchinson, G; Alamillo-Ferrer, C; Bures, J in [Hutchinson, George; Alamillo-Ferrer, Carla; Bures, Jordi] Univ Manchester, Dept Chem, Manchester M13 9PL, Lancs, England published Mechanistically Guided Design of an Efficient and Enantioselective Aminocatalytic alpha-Chlorination of Aldehydes in 2021.0, Cited 18.0. The Name is Benzophenone. Through research, I have a further understanding and discovery of 119-61-9.
The enantioselective aminocatalytic alpha-chlorination of aldehydes is a challenging reaction because of its tendency to proceed through neutral intermediates in unselective pathways. Herein we report the rational shift to a highly selective reaction pathway involving charged intermediates using hexafluoroisopropanol as solvent. This change in mechanism has enabled us to match and improve upon the yields and enantioselectivities displayed by previous methods while using cheaper aminocatalysts and chlorinating agents, 80-95% less amount of catalyst, convenient temperatures, and shorter reaction times.
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Reference:
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