An article Manganese-Mediated C-C Bond Formation: Alkoxycarbonylation of Organoboranes WOS:000636740800006 published article about PALLADIUM-CATALYZED ALKOXYCARBONYLATION; ALKYL IODIDES; ARYL HALIDES; METAL-FREE; CARBONYLATION; DECARBONYLATION; COMPLEXES; CHEMISTRY; EFFICIENT; CLEAVAGE in [van Putten, Robbert; Filonenko, Georgy A.; Krieger, Annika M.; Pidko, Evgeny A.] Delft Univ Technol, Inorgan Syst Engn, Dept Chem Engn, Fac Appl Sci, NL-2629 HZ Delft, Netherlands; [Lutz, Martin] Univ Utrecht, Bijvoet Ctr Biomol Res, Crystal & Struct Chem, NL-3584 CH Utrecht, Netherlands in 2021.0, Cited 41.0. Application In Synthesis of Benzophenone. The Name is Benzophenone. Through research, I have a further understanding and discovery of 119-61-9
Alkoxycarbonylations are important and versatile reactions that result in the formation of a new C-C bond. Herein, we report on a new and halide-free alkoxycarbonylation reaction that does not require the application of an external carbon monoxide atmosphere. Instead, manganese carbonyl complexes and organo(alkoxy)borate salts react to form an ester product containing the target C-C bond. The required organo(alkoxy)borate salts are conveniently generated from the stoichiometric reaction of an organoborane and an alkoxide salt and can be telescoped without purification. The protocol leads to the formation of both aromatic and aliphatic esters and gives complete control over the ester’s substitution (e.g., OMe, (OBu)-Bu-t, OPh). A reaction mechanism was proposed on the basis of stoichiometric reactivity studies, spectroscopy, and DFT calculations. The new chemistry is particularly relevant for the field of Mn(I) catalysis and clearly points to a potential pathway toward irreversible catalyst deactivation.
Welcome to talk about 119-61-9, If you have any questions, you can contact van Putten, R; Filonenko, GA; Krieger, AM; Lutz, M; Pidko, EA or send Email.. Application In Synthesis of Benzophenone
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