Recently I am researching about BOND ACTIVATION; METAL-IONS; DECARBOXYLATION; MECHANISMS, Saw an article supported by the American Chemical Society Petroleum Research FundAmerican Chemical Society [59763-ND6]; Australian Research CouncilAustralian Research Council [DP180101187]; Department of Chemistry and Biochemistry, Northern Illinois University. Published in WILEY in HOBOKEN ,Authors: Piacentino, EL; Rodriguez, E; Parker, K; Gilbert, TM; O’Hair, RAJ; Ryzhov, V. The CAS is 104-21-2. Through research, I have a further understanding and discovery of 4-Methoxybenzyl acetate. Category: thiomorpholine
Gas-phase C?C coupling reactions mediated by Ni (II) complexes were studied using a linear quadrupole ion trap mass spectrometer. Ternary nickel cationic carboxylate complexes, [(phen)Ni (OOCR1)](+) (where phen = 1,10-phenanthroline), were formed by electrospray ionization. Upon collision-induced dissociation (CID), they extrude CO2 forming the organometallic cation [(phen)Ni(R-1)](+), which undergoes gas-phase ion-molecule reactions (IMR) with acetate esters CH3COOR2 to yield the acetate complex [(phen)Ni (OOCCH3)](+) and a C?C coupling product R-1-R-2. These Ni(II)/phenanthroline-mediated coupling reactions can be performed with a variety of carbon substituents R-1 and R-2 (sp(3), sp(2), or aromatic), some of them functionalized. Reaction rates do not seem to be strongly dependent on the nature of the substituents, as sp(3)-sp(3) or sp(2)-sp(2) coupling reactions proceed rapidly. Experimental results are supported by density functional theory calculations, which provide insights into the energetics associated with the C?C bond coupling step.
Welcome to talk about 104-21-2, If you have any questions, you can contact Piacentino, EL; Rodriguez, E; Parker, K; Gilbert, TM; O’Hair, RAJ; Ryzhov, V or send Email.. Category: thiomorpholine
Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem