An article Synthesis and Reactivity of Acyclic Germanimines: Silyl Rearrangement and Cycloadditions WOS:000661306200072 published article about H BOND ACTIVATION; CRYSTAL-STRUCTURE; STRUCTURAL-CHARACTERIZATION; TERMINAL ALKYNES; COMPLEXES; GERMANIUM(II); BEHAVIOR; AMIDINATE; GERMENES; GERMYLENES in [Evans, Matthew J.; Burke, Finlay M.; Chapple, Peter M.; Fulton, J. Robin] Victoria Univ Wellington, Sch Chem & Phys Sci, Wellington 6012, New Zealand in 2021.0, Cited 75.0. Recommanded Product: 119-61-9. The Name is Benzophenone. Through research, I have a further understanding and discovery of 119-61-9
We report the synthesis of aromatic germanimines [(HMDS)(2)Ge=NAr] (Ar = Ph, Mes, Dipp; Mes = 2,4,6-Me3C6H2, Dipp = 2,6-iPr(2)C(6)H(3)) and an investigation into their associated reactivity. [(HMDS)(2)Ge=NPh] decomposes above -30 degrees C, while [(HMDS)(2)Ge=NDipp] engages in an intramolecular reaction at 60 degrees C. [(HMDS)(2)Ge=NMes] was shown to rearrange via a 1,3-silyl migration to give [(HMDS){(SiMe3)-(Mes)N}Ge(NSiMe3)] in a 1:7 equilibrium mixture at room temperature. These latter germanimines react with unsaturated polar substrates such as CO2, ketones, and arylisocyanate via a [2 + 2] cycloaddition pathway.
Recommanded Product: 119-61-9. Welcome to talk about 119-61-9, If you have any questions, you can contact Evans, MJ; Burke, FM; Chapple, PM; Fulton, JR or send Email.
Reference:
Thiomorpholine – Wikipedia,
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