Name: Benzophenone. Recently I am researching about N-HETEROCYCLIC CARBENE; DIPALLADIUM COMPLEXES; HECK REACTION; REDUCTION; NITROARENES, Saw an article supported by the Ministry of Science and Technology, TaiwanMinistry of Science and Technology, Taiwan [MOST109-2113-M-002-010-MY2]. Published in AMER CHEMICAL SOC in WASHINGTON ,Authors: Lin, SCA; Su, BK; Liu, YH; Peng, SM; Liu, ST. The CAS is 119-61-9. Through research, I have a further understanding and discovery of Benzophenone
Complexation of L [L = 5-phenyl-2,8-di-2-pyridinyl-anthyridine] with [Pd(CH3CN)(4)](BF4)(2) and [Pd(CH3CN)(3)Cl](BF4) in a molar ratio of 1:2 rendered the corresponding dinuclear complexes [Pd2L (CH3CN)(4)](BF4)(4) (1) and [Pd2L (CH3CN)(2)Cl-2](BF4)(2) (2), respectively. However, treatment of L with (COD)PdCl2 followed by anion exchange yielded a tetranuclear complex [Pd4L3Cl4](PF6)(4)(4a). Structures of these complexes are characterized by both spectroscopy and X-ray crystallography. Interconversion of these three complexes was studied via the manipulation of stoichiometric ratio of ligand to metal precursor. The catalytic activity of these complexes for carbonylative Suzuki-Miyaura cross-coupling was investigated. Complex 2 shows an excellent catalytic activity on the reaction of aryl iodide with arylboronic acid in the presence of atmospheric pressure of CO to give the corresponding benzophenones.
Name: Benzophenone. Welcome to talk about 119-61-9, If you have any questions, you can contact Lin, SCA; Su, BK; Liu, YH; Peng, SM; Liu, ST or send Email.
Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem