Rajkiewicz, AA; Skowerski, K; Trzaskowski, B; Kajetanowicz, A; Grela, K in [Rajkiewicz, Adam A.; Kajetanowicz, Anna; Grela, Karol] Univ Warsaw, Fac Chem, Biol & Chem Res Ctr, Zwirki & Wigury St 101, PL-02089 Warsaw, Poland; [Skowerski, Krzysztof] Apeiron Synth SA, Dunska 9, PL-54427 Wroclaw, Poland; [Trzaskowski, Bartosz] Univ Warsaw, Ctr New Technol, PL-02097 Warsaw, Poland published 2-Methyltetrahydrofuran as a Solvent of Choice for Spontaneous Metathesis/Isomerization Sequence in 2019, Cited 52. Safety of Anthrone. The Name is Anthrone. Through research, I have a further understanding and discovery of 90-44-8.
A new protocol for ring-closing metathesis/isomerization sequence was developed. The reactions of selected dienes were performed in overheated 2-methyltetrahydrofuran at 120 degrees C and provided a wide range of cyclic vinyl ethers and amides with good yields and selectivities. Computational analysis suggests that the relative yield of products depends on a thermodynamically driven process on the basis of relative stabilities of isomers.
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Reference:
Thiomorpholine – Wikipedia,
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