An article Triplet Excitons Quenching By Doublet Centers in a Nanoreactor with an External Magnetic Field WOS:000647943800009 published article about ELECTRON-SPIN POLARIZATION; PAIRS; MAGNETOCONDUCTANCE; RECOMBINATION; ANNIHILATION; RESONANCE; STATES in [Kucherenko, M. G.; Penkov, S. A.] Orenburg State Univ, Orenburg 460018, Russia in 2021.0, Cited 41.0. Recommanded Product: Benzophenone. The Name is Benzophenone. Through research, I have a further understanding and discovery of 119-61-9
The process of spin-selective quenching of a triplet (T) exciton by a fixed spin doublet (D) center in an organic semiconductor nanoparticle (anthracene, tetracene, MEH-PPV) was studied. Random walks of the T-exciton in a spherical nanovolume of a crystal or polymer globule were modeled based on the solution of the Neumann boundary diffusion condition. Time dependences of the spin-nonselective quenching rate of T-excitations were calculated for different values of geometric and diffusion parameters. Taking into account the spin dynamics of T-D-pair reagents allowed calculating magnetic field effects of T-D-quenching rate, which showed a strong influence of the nanoparticles size and initial position of the T-exciton and doublet sink on the absolute value of the effect. The obtained radial dependences of the magnetic field modulation of the quenching efficiency can be approximated by a superposition of two exponents.
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