Recently I am researching about MICHAEL ADDITION; SULFONAMIDE POLYMERS; ORGANOCATALYSTS; NITROALKENES; DERIVATIVES; QUATERNARY; ANTHRONE, Saw an article supported by the JSPS KAKENHIMinistry of Education, Culture, Sports, Science and Technology, Japan (MEXT)Japan Society for the Promotion of ScienceGrants-in-Aid for Scientific Research (KAKENHI) [JP15H00732, JP15K05517]. Quality Control of Anthrone. Published in ELSEVIER in AMSTERDAM ,Authors: Kumpuga, BT; Itsuno, S. The CAS is 90-44-8. Through research, I have a further understanding and discovery of Anthrone
Chiral polyurethanes of cinchona alkaloid were synthesized via repetitive Mizoroki-Heck (MH) coupling reaction. The Pd-catalyzed polycondensation of cinchona urethane dimers and aromatic diiodides afforded the chiral polyurethanes. The chiral polyurethane bearing free OH group at the C6′ position of the quinoline ring in the cinchona alkaloid unit showed high catalytic activities and excellent enantioselectivities (up to 97% ee) in the Michael addition reactions.
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Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem