Recently I am researching about NITROGEN-CONTAINING COMPOUNDS; CROSS-COUPLING REACTIONS; N BONDS; AMIDATION; QUINOLINE; CONSTRUCTION; QUINAZOLINE; DERIVATIVES; CASCADE; SALTS, Saw an article supported by the Natural Science Foundation of Shandong ProvinceNatural Science Foundation of Shandong Province [ZR2020MB009, ZR2019MB009]; Key Research and Development Program of Shandong Province [2019GSF108089]; National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21672046, 21372054]; Huancui District of Weihai City. Recommanded Product: 119-61-9. Published in WILEY-V C H VERLAG GMBH in WEINHEIM ,Authors: Chen, WQ; Li, CY; Li, HJ; Wu, YC. The CAS is 119-61-9. Through research, I have a further understanding and discovery of Benzophenone
The formation of C-N bonds is a fundamental bond construction in organic synthesis. In this context, a [RhCp*Cl-2](2)/AgSbF6 system was developed for the C2-amination of ketoximes with anthranils with the use of Piv(2)O as a promoter. Piv(2)O played an important role in the generation of catalytically active species with [RhCp*Cl-2](2). The oxime unit was revealed to be effective chelating groups to activate the aryl C-H bond. The amination shows a wide substrates scope, and several important functional groups were tolerated under the benign reaction conditions.
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Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem