Matador, E; Iglesias-Siguenza, J; Monge, D; Merino, P; Fernandez, R; Lassaletta, JM in [Lassaletta, Jose M.] US, CSIC, Inst Invest Quim, C Amer Vespucio 49, Seville 41092, Spain; [Lassaletta, Jose M.] CINQA, ORFEO, Ctr Innovac Quim Avanzada, C Amer Vespucio 49, Seville 41092, Spain; [Matador, Esteban; Iglesias-Siguenza, Javier; Monge, David; Fernandez, Rosario] Univ Seville, Dept Quim Organ, C Prof Garcia Gonzalez 1, Seville 41012, Spain; [Matador, Esteban; Iglesias-Siguenza, Javier; Monge, David; Fernandez, Rosario] CINQA, ORFEO, Ctr Innovac Quim Avanzada, C Prof Garcia Gonzalez 1, Seville 41012, Spain; [Merino, Pedro] Univ Zaragoza, CSIC, Inst Biocomputac & Fis Sistemas Complejos BIFI, Zaragoza 50009, Spain published Enantio- and Diastereoselective Nucleophilic Addition of N-tert-Butylhydrazones to Isoquinolinium Ions through Anion-Binding Catalysis in 2021.0, Cited 59.0. Category: thiomorpholine. The Name is 3-Nitrobenzaldehyde. Through research, I have a further understanding and discovery of 99-61-6.
A highly enantio- and diastereoselective thiourea-catalyzed dearomatization of isoquinolines employing N-tert-butylhydrazones as neutral alpha-azo carbanions and masked acyl anion equivalents has been developed. Experimental and computational data supports the generation of highly ordered complexes wherein the chloride behaves as a template for the catalyst, the hydrazone reagent, and the isoquinolinium cation, providing excellent stereocontrol in the formation of two contiguous stereogenic centers. The ensuing selective and high-yielding transformations provide appealing dihydroisoquinoline derivatives.
Welcome to talk about 99-61-6, If you have any questions, you can contact Matador, E; Iglesias-Siguenza, J; Monge, D; Merino, P; Fernandez, R; Lassaletta, JM or send Email.. Category: thiomorpholine
Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem