An article Carboxyboronate as a Versatile In Situ CO Surrogate in Palladium-Catalyzed Carbonylative Transformations WOS:000601066000001 published article about ARYL BROMIDES; FORMIC-ACID; N-FORMYLSACCHARIN; CARBOXYLIC-ACIDS; HALIDES; EFFICIENT; GENERATION; REDUCTION; DERIVATIVES; MOLECULES in [Tien, Chieh-Hung; Trofimova, Alina; Holownia, Aleksandra; Kwak, Branden S.; Yudin, Andrei K.] Univ Toronto, Dept Chem, Davenport Res Labs, 80 St George St, Toronto, ON M5S 3H6, Canada; [Larson, Reed T.] Merck & Co Inc, Proc Res & Dev, Rahway, NJ 07065 USA in 2021.0, Cited 101.0. Formula: C13H10O. The Name is Benzophenone. Through research, I have a further understanding and discovery of 119-61-9
The application of carboxy-MIDA-boronate (MIDA=N-methyliminodiacetic acid) as an in situ CO surrogate for various palladium-catalyzed transformations is described. Carboxy-MIDA-boronate was previously shown to be a bench-stable boron-containing building block for the synthesis of borylated heterocycles. The present study demonstrates that, in addition to its utility as a precursor to heterocycle synthesis, carboxy-MIDA-boronate is an excellent in situ CO surrogate that is tolerant of reactive functionalities such as amines, alcohols, and carbon-based nucleophiles. Its wide functional-group compatibility is highlighted in the palladium-catalyzed aminocarbonylation, alkoxycarbonylation, carbonylative Sonogashira coupling, and carbonylative Suzuki-Miyaura coupling of aryl halides. A variety of amides, esters, (hetero)aromatic ynones, and bis(hetero)aryl ketones were synthesized in good-to-excellent yields in a one-pot fashion.
Formula: C13H10O. About Benzophenone, If you have any questions, you can contact Tien, CH; Trofimova, A; Holownia, A; Kwak, BS; Larson, RT; Yudin, AK or concate me.
Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem