SDS of cas: 90-44-8. Recently I am researching about ELECTRON-TRANSFER; METAL-FREE; RADICALS; BOND; HETEROARENES; GENERATION; ARYLATION; PHENOLS, Saw an article supported by the German Science Foundation (DFG)German Research Foundation (DFG) [GRK 1626, KO 1537/18-1]. Published in ROYAL SOC CHEMISTRY in CAMBRIDGE ,Authors: Schmalzbauer, M; Ghosh, I; Konig, B. The CAS is 90-44-8. Through research, I have a further understanding and discovery of Anthrone
The tricyclic aromatic ketone 9-anthrone and its derivatives are under basic conditions in equilibrium with their corresponding anionic forms. Unlike the neutral species, the 9-anthrolate anions can be excited by blue LED light and thus, are able to initiate a photoinduced electron transfer (PET) reaction. To demonstrate the synthetic applicability of the catalytic system, various (hetero)aryl chlorides were converted in C-C and C-Het bond-forming reactions affording the corresponding arylation products in moderate to excellent yields. The reactions proceed under very mild conditions without the need for a sacrificial electron donor. Besides 9-anthrone, other closely related derivatives were synthesised and investigated concerning their ability to catalyse demanding reductive transformations. Based on spectroscopic findings and radical trapping experiments a conceivable mechanism is proposed.
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Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem