Recently I am researching about GAS-TRANSPORT PROPERTIES; POLYIMIDES; MEMBRANES; POLYMERS, Saw an article supported by the National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21564005, 51663011]; Research Program of Jiangxi Science and Technology Department [20192BBE50049]; Ground Project for Science and Technology of Jiangxi Universities [KJLD14022]; Research Program of Jiangxi Province Department of Education [GJJ14236]; Graduate Student Innovation Foundation of Jiangxi Normal University [YC2019-B041]. Published in SAGE PUBLICATIONS LTD in LONDON ,Authors: Zhang, ZY; Huang, ZZ; Pan, Y; Song, C. The CAS is 90-44-8. Through research, I have a further understanding and discovery of Anthrone. Category: thiomorpholine
A new diamine bearing flexible ether, rigid pyridine, and bulky anthrone pendent group, 10,10-bis[4-(4-amino-2-pyridinoxy)phenyl]-9(10H)-anthrone (BAPPA), was prepared in three steps from anthrone. BAPPA was reacted with six conventional aromatic dianhydrides in N, N-dimethylacetamide (DMAc) to form the corresponding new poly(ether imide)s (PEIs) via the poly(ether amic acid) (PEAA) precursors with inherent viscosities ranging from 0.85 dL g(-1) to 1.26 dL g(-1) and thermal imidization. All the PEAAs could be cast from DMAc solution and thermally converted into transparent, flexible, and tough PEI films with tensile strength of 72.2-112.4 MPa, tensile modulus of 1.8-2.1 GPa, and elongation at break of 10-18%. These PEIs were predominantly amorphous and displayed excellent thermal stability with the glass transition temperature of 290-388 degrees C, the 5% weight loss temperature of 480-514 degrees C, and the residue of 68-43% at 800 degrees C in nitrogen. The PEIs derived from 1,4-bis(3,4-dicarboxyphenoxy)benzene dianhydride and 4,4 ‘-hexafluoroisopropylidenediphathalic anhydride exhibited excellent solubility in organic solvents such as N-methyl-2-pyrrolidinone, DMAc, N, N-dimethylformamide, pyridine, and even in tetrahydrofuran. Meanwhile, these PEIs also exhibited high optical transparency with the ultraviolet cutoff wavelength in the 374-427 nm range and the wavelength of 80% transparency in the range of 468-493 nm.
Category: thiomorpholine. About Anthrone, If you have any questions, you can contact Zhang, ZY; Huang, ZZ; Pan, Y; Song, C or concate me.
Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem