An article Synthesis of cis-Oriented Vicinal Diphenylethylenes through a Lewis Acid-Promoted Annulation of Oxotriphenylhexanoates WOS:000670661000012 published article about STEREOSELECTIVE-SYNTHESIS; ASYMMETRIC-SYNTHESIS; STILBENE OLIGOMERS; POTENT ANTICANCER; NATURAL-PRODUCTS; IONIC LIQUIDS; RESVERATROL; CYCLIZATION; ROCAGLAMIDE; SILVESTROL in [Kamlar, Martin; Henriksson, Elin; Sunden, Henrik] Chalmers Univ Technol, Dept Chem & Chem Engn, S-41296 Gothenburg, Sweden; [Kamlar, Martin] Charles Univ Prague, Fac Sci, Dept Organ Chem, Prague 128432, Czech Republic; [Cisarova, Ivana] Charles Univ Prague, Fac Sci, Dept Inorgan Chem, Prague 128432, Czech Republic; [Malo, Marcus; Sunden, Henrik] Univ Gothenburg, Dept Chem & Mol Biol, SE-41296 Gothenburg, Sweden in 2021.0, Cited 65.0. The Name is Benzophenone. Through research, I have a further understanding and discovery of 119-61-9. Recommanded Product: Benzophenone
This study explores the synthesis of cyclic cis-vicinal phenyl ethylenes from oxotriphenylhexanoates. The reaction is a BBr3-promoted cyclization of 1,6-ketoesters (1) to five-membered diketo compounds (2). The synthesis is interesting as it constitutes one of the few examples of modular stereoselective synthesis of structures with a cis-oriented vicinal diphenylethylene. The core structure of 2 can be smoothly derivatized, which makes it a promising synthetic building block for further stereoselective synthetic applications.
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