An article Copper and copper-manganese 1D coordination polymers: Synthesis optimization, crystal structure and preliminary studies as catalysts for Baylis-Hillman reactions WOS:000588151400016 published article about LIGAND-ACCELERATED CATALYSIS; IMINODIACETIC ACID; MAGNETIC-PROPERTIES; METAL; SPECTROSCOPY; CHEMISTRY; ADDUCTS; WATER; IONS; IRON in [Dutra de Andrade, Julyanna Candido; Trajano Silva, Lucas Araujo; Lima-Junior, Claudio Gabriel; Araujo de Almeida Vasconcellos, Mario Luiz; da Silva, Fausthon Fred] Univ Fed Paraiba, Dept Quim, BR-58051900 Joao Pessoa, Paraiba, Brazil; [Chojnacki, Jaroslaw] Gdansk Univ Technol, Dept Inorgan Chem, PL-80233 Gdansk, Poland; [da Silva, R. B.] Univ Fed Rio Grande do Norte, Dept Fis, BR-59078900 Natal, RN, Brazil; [Alves Junior, Severino] Univ Fed Pernambuco, Dept Quim Fundamental, BR-50590470 Recife, PE, Brazil in 2021.0, Cited 56.0. SDS of cas: 99-61-6. The Name is 3-Nitrobenzaldehyde. Through research, I have a further understanding and discovery of 99-61-6
This work reports the influence of experimental parameters (pH and counter-ion) in the synthesis of the 1D coordination polymer [Cu(IDA)(H2O)(2)](n). (IDA = iminodiacetate), named here Cu-IDA. Copper-manganese bimetallic coordination polymers were also obtained by isomorphic replacement into Cu-IDA structure, with different molar ratio of Cu2+ and Mn2+ ions, denoted here as Cu/Mn-IDA (0.9/0.1; 0.7/0.3 and 0.5/0.5). New coordination polymers are isostructural to Cu-IDA and amounts of manganese atoms inserted into crystalline structure were evaluated by single-crystal X-ray diffraction and Rietveld refinement. All coordination polymers obtained were also characterized by infrared absorption spectroscopy and thermogravimetric analysis. Homometallic and bimetallic compounds were evaluated as catalysts for Baylis-Hillman reaction with yields and reaction times comparable or superior to those in the literature. Compounds containing manganese cations shows higher catalytic performance, especially Cu/Mn-IDA (0.9/0.1) with yield 91% in 5 h of reaction. Results also indicate an important role played by the metallic centre in the catalytic mechanism.
SDS of cas: 99-61-6. About 3-Nitrobenzaldehyde, If you have any questions, you can contact de Andrade, JCD; Silva, LAT; Lima, CG; Chojnacki, J; Vasconcellos, MLAD; da Silva, RB; Alves, SA; da Silva, FF or concate me.
Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem