I found the field of Biochemistry & Molecular Biology; Chemistry; Spectroscopy very interesting. Saw the article Gas-phase functionalized carbon-carbon coupling reactions catalyzed by Ni (II) complexes published in 2019. HPLC of Formula: C10H12O3, Reprint Addresses Ryzhov, V (corresponding author), Northern Illinois Univ, Dept Chem & Biochem, De Kalb, IL 60115 USA.; O’Hair, RAJ (corresponding author), Univ Melbourne, Bio Inst 21, Melbourne, Vic 3010, Australia.; O’Hair, RAJ (corresponding author), Univ Melbourne, Sch Chem, Melbourne, Vic 3010, Australia.. The CAS is 104-21-2. Through research, I have a further understanding and discovery of 4-Methoxybenzyl acetate
Gas-phase C?C coupling reactions mediated by Ni (II) complexes were studied using a linear quadrupole ion trap mass spectrometer. Ternary nickel cationic carboxylate complexes, [(phen)Ni (OOCR1)](+) (where phen = 1,10-phenanthroline), were formed by electrospray ionization. Upon collision-induced dissociation (CID), they extrude CO2 forming the organometallic cation [(phen)Ni(R-1)](+), which undergoes gas-phase ion-molecule reactions (IMR) with acetate esters CH3COOR2 to yield the acetate complex [(phen)Ni (OOCCH3)](+) and a C?C coupling product R-1-R-2. These Ni(II)/phenanthroline-mediated coupling reactions can be performed with a variety of carbon substituents R-1 and R-2 (sp(3), sp(2), or aromatic), some of them functionalized. Reaction rates do not seem to be strongly dependent on the nature of the substituents, as sp(3)-sp(3) or sp(2)-sp(2) coupling reactions proceed rapidly. Experimental results are supported by density functional theory calculations, which provide insights into the energetics associated with the C?C bond coupling step.
HPLC of Formula: C10H12O3. Bye, fridends, I hope you can learn more about C10H12O3, If you have any questions, you can browse other blog as well. See you lster.
Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem