Recently I am researching about AEROBIC OXIDATION; ANODIC-OXIDATION; ORGANIC ELECTROSYNTHESIS; N-HYDROXYPHTHALIMIDE; ELECTRON-TRANSFER; PRIMARY ALCOHOLS; REDOX CATALYSTS; P-XYLENE; EFFICIENT; HYDROCARBONS, Saw an article supported by the Fundamental Research Funds for the Central Universities in China [020514380224]; Natural Science Foundation of Jiangsu ProvinceNatural Science Foundation of Jiangsu Province [BK20180321]; Innovation & Entrepreneurship Talents Plan of Jiangsu Province. Published in ROYAL SOC CHEMISTRY in CAMBRIDGE ,Authors: Sun, YX; Li, XS; Yang, M; Xu, WT; Xie, J; Ding, MN. The CAS is 90-44-8. Through research, I have a further understanding and discovery of Anthrone. Formula: C14H10O
The selective oxidation of C-H bond is critical for feedstock manufacturing in chemical industry. Current strategies typically involve the use of oxygen or peroxide as the oxidation reagent under high temperature, which sets severe challenges in production sustainability and industrial safety. Herein, we demonstrate an environmental-friendly and safe electrocatalytic strategy for the selective oxidation of benzyl group to ketones at ambient conditions, while using water as the sole oxygen source. Water addition reduces the onset potential of anodic C-H oxidation, and produces 1-tetralone with satisfying conversion and excellent ketone to alcohol ratio. Layered MnO2 catalysts (with rich oxygen vacancies) further adjust the water affinity and facilitate the oxidation, leading to a significantly improved faradaic efficiency.
Welcome to talk about 90-44-8, If you have any questions, you can contact Sun, YX; Li, XS; Yang, M; Xu, WT; Xie, J; Ding, MN or send Email.. Formula: C14H10O
Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem