Chemical Properties and Facts of 3-Nitrobenzaldehyde

Welcome to talk about 99-61-6, If you have any questions, you can contact Ma, YCA; Luo, JY; Zhang, SC; Lu, SH; Du, GF; He, L or send Email.. SDS of cas: 99-61-6

SDS of cas: 99-61-6. Authors Ma, YCA; Luo, JY; Zhang, SC; Lu, SH; Du, GF; He, L in ROYAL SOC CHEMISTRY published article about in [Ma, Yu-Chuan; Luo, Jin-Yun; Lu, Shu-Hui; Du, Guang-Fen; He, Lin] Shihezi Univ, Key Lab Green Proc Chem Engn Xinjiang, Bingtuan Sch Chem & Chem Engn, Shihezi Shi 832000, Xinjiang Uygur, Peoples R China; [Zhang, Shi-Chu] Shihezi Univ, Coll Sci, Shihezi Shi 832000, Xinjiang Uygur, Peoples R China in 2021.0, Cited 90.0. The Name is 3-Nitrobenzaldehyde. Through research, I have a further understanding and discovery of 99-61-6

An N-heterocyclic carbene-catalyzed synthesis of dibenzofulvenes and fluorenyl alcohols was developed. In the presence of 10 mol% NHC (1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene) and 4 angstrom molecular sieves, 9-(trimethylsilyl)fluorene undergoes an olefination reaction with aldehydes to produce dibenzofulvenes in 43-99% yields. However, on reducing the NHC loading to 1 mol% and with the addition of water, 9-(trimethylsilyl)fluorene selectively undergoes nucleophilic addition with aldehydes to afford fluorenyl alcohols in 40-95% yields.

Welcome to talk about 99-61-6, If you have any questions, you can contact Ma, YCA; Luo, JY; Zhang, SC; Lu, SH; Du, GF; He, L or send Email.. SDS of cas: 99-61-6

Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem