Recently I am researching about MORITA-BAYLIS-HILLMAN; CONJUGATED NITROALKENES; FUSED FURANS; ACCESS; IMIDAZOLES; AMIDINES; INSOMNIA; SYNTHONS; ADDUCTS, Saw an article supported by the SERB, DST India; CSIR IndiaCouncil of Scientific & Industrial Research (CSIR) – India. Recommanded Product: 2-Aminobenzamide. Published in PERGAMON-ELSEVIER SCIENCE LTD in OXFORD ,Authors: Nair, DK; Sivanandan, ST; Kendrekar, P; Namboothiri, INN. The CAS is 88-68-6. Through research, I have a further understanding and discovery of 2-Aminobenzamide
A [4+3] annulation of o-phenylenediamines with primary nitroallylic acetates affords nitrobenzodiazepines (NBDZs) in good to excellent yield. The reaction which proceeds in MeOH at room temperature in the absence of any base or catalyst involves a cascade S(N)2 N-nitroallylation-intramolecular aza-Michael addition sequence. In the case of mono-N-arylated o-phenylenediamines and o-aminobenzamides, the reaction stops at the S(N)2 stage affording nitroallylic amines. On the other hand, reaction of o-aminobenzamides with secondary nitroallylic acetates delivers S(N)2′ products. Formation of stable S(N)2 and S(N)2′ products provides insights into the reactivity of primary and secondary nitroallylic acetates and also the mechanism of formation of nitrobenzodiazepines. (C) 2019 Elsevier Ltd. All rights reserved.
Recommanded Product: 2-Aminobenzamide. Welcome to talk about 88-68-6, If you have any questions, you can contact Nair, DK; Sivanandan, ST; Kendrekar, P; Namboothiri, INN or send Email.
Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem