Application In Synthesis of 2-Aminobenzamide. In 2021 ANGEW CHEM INT EDIT published article about CIRCULARLY-POLARIZED LUMINESCENCE; ASYMMETRIC-SYNTHESIS; BINOL; CRYSTALLINE; CONSTRUCTION; STABILITY; MOLECULES; STRATEGY; PLATFORM; DESIGN in [Hou, Bang; Yang, Shi; Han, Xing; Tang, Xianhui; Liu, Yan; Cui, Yong] Shanghai Jiao Tong Univ, Frontiers Sci Ctr Transformat Mol, Sch Chem & Chem Engn, Shanghai 200240, Peoples R China; [Hou, Bang; Yang, Shi; Han, Xing; Tang, Xianhui; Liu, Yan; Cui, Yong] Shanghai Jiao Tong Univ, State Key Lab Met Matrix Composites, Shanghai 200240, Peoples R China; [Yang, Kuiwei; Jiang, Jianwen] Natl Univ Singapore, Dept Chem & Biomol Engn, Singapore 117576, Singapore in 2021, Cited 78. The Name is 2-Aminobenzamide. Through research, I have a further understanding and discovery of 88-68-6.
3D covalent organic frameworks (COFs) with well-defined porous channels are shown to be capable of inducing chiral molecular catalysts from non-enantioselective to highly enantioselective in catalyzing organic transformations. By condensations of a tetrahedral tetraamine and two linear dialdehydes derived from enantiopure 1,1 ‘-binaphthol (BINOL), two chiral 3D COFs with a 9-fold or 11-fold interpenetrated diamondoid framework are prepared. Enhanced Bronsted acidity was observed for the chiral BINOL units that are uniformly distributed within the tubular channels compared to the non-immobilized acids. This facilitates the Bronsted acid catalysis of cyclocondensation of aldehydes and anthranilamides to produce 2,3-dihydroquinazolinones. DFT calculations show the COF catalyst provides preferential secondary interactions between the substrate and framework to induce enantioselectivities that are not achievable in homogeneous systems.
Application In Synthesis of 2-Aminobenzamide. About 2-Aminobenzamide, If you have any questions, you can contact Hou, B; Yang, S; Yang, KW; Han, X; Tang, XH; Liu, Y; Jiang, JW; Cui, Y or concate me.
Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem