An article Single-Crystal Cobalt Phosphide Nanorods as a High-Performance Catalyst for Reductive Amination of Carbonyl Compounds WOS:000651113700014 published article about NICKEL PHOSPHIDE; HYDROGEN EVOLUTION; PRIMARY AMINES; DOPED CARBON; CHEMOSELECTIVE HYDROGENATION; SELECTIVE HYDROGENATION; MOLECULAR-HYDROGEN; GENERAL-SYNTHESIS; NANOPARTICLES; EFFICIENT in [Sheng, Min; Fujita, Shu; Yamaguchi, Sho; Mizugaki, Tomoo; Mitsudome, Takato] Osaka Univ, Grad Sch Engn Sci, Dept Mat Engn Sci, Osaka 5608531, Japan; [Yamasaki, Jun] Osaka Univ, Res Ctr Ultrahigh Voltage Electron Microscopy, Ibaraki, Osaka 5670047, Japan; [Nakajima, Kiyotaka] Hokkaido Univ, Inst Catalysis, Sapporo, Hokkaido 0010021, Japan; [Yamazoe, Seiji] Tokyo Metropolitan Univ, Dept Chem, Tokyo 1920397, Japan; [Mizugaki, Tomoo] Osaka Univ, Innovat Catalysis Sci Div, Inst Open & Transdisciplinary Res Initiat ICS OTR, Suita, Osaka 5650871, Japan in 2021.0, Cited 50.0. The Name is Benzophenone. Through research, I have a further understanding and discovery of 119-61-9. SDS of cas: 119-61-9
The development of metal phosphide catalysts for organic synthesis is still in its early stages. Herein, we report the successful synthesis of single-crystal cobalt phosphide nanorods (Co2P NRs) containing coordinatively unsaturated Co-Co active sites, which serve as a new class of air-stable, highly active, and reusable heterogeneous catalysts for the reductive amination of carbonyl compounds. The Co2P NR catalyst showed high activity for the transformation of a broad range of carbonyl compounds to their corresponding primary amines using an aqueous ammonia solution or ammonium acetate as a green amination reagent at 1 bar of H-2 pressure; these conditions are far milder than previously reported. The air stability and high activity of the Co2P NRs is noteworthy, as conventional Co catalysts are air-sensitive (pyrophorous) and show no activity for this transformation under mild conditions. P-alloying is therefore of considerable importance for nanoengineering air-stable and highly active non-noble-metal catalysts for organic synthesis.
SDS of cas: 119-61-9. Welcome to talk about 119-61-9, If you have any questions, you can contact Sheng, M; Fujita, S; Yamaguchi, S; Yamasaki, J; Nakajima, K; Yamazoe, S; Mizugaki, T; Mitsudome, T or send Email.
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