Computed Properties of C13H10O. In 2021.0 ANGEW CHEM INT EDIT published article about SI-H; HYDROSILYLATION; HYDROAMINATION; ACTIVATION; REDUCTION; COMPLEXES; REACTIVITY; DIOXIDE; CO2 in [Adet, Nicolas; Specklin, David; Gourlaouen, Christophe; Damiens, Thibault; Jacques, Beatrice; Dagorne, Samuel] Univ Strasbourg, Inst Chim Strasbourg, CNRS, 1 Rue Blaise Pascal, F-67000 Strasbourg, France; [Wehmschulte, Rudolf J.] Florida Inst Technol, Chem Program, 150 West Univ Blvd, Melbourne, FL 32901 USA in 2021.0, Cited 61.0. The Name is Benzophenone. Through research, I have a further understanding and discovery of 119-61-9.
The employment of the hexyl-substituted anion [HexCB(11)Cl(11)](-) allowed the synthesis of a Zn-II species, Zn[HexCB(11)Cl(11)](2), 3, in which the Zn2+ cation is only weakly coordinated to two carborate counterions and that is soluble in low polarity organic solvents such as bromobenzene. DOSY NMR studies show the facile displacement of at least one of the counterions, and this near nakedness of the cation results in high catalytic activity in the hydrosilylation of 1-hexene and 1-methyl-1cyclohexene. Fluoride ion affinity (FIA) calculations reveal a solution Lewis acidity of 3 (FIA=262.1 kJ mol(-1)) that is higher than that of the landmark Lewis acid B(C6F5)(3) (FIA=220.5 kJ mol(-1)). This high Lewis acidity leads to a high activity in catalytic CO2 and Ph2CO reduction by Et3SiH and hydrogenation of 1,1-diphenylethylene using 1,4-cyclohexadiene as the hydrogen source. Compound 3 was characterized by multinuclear NMR spectroscopy, mass spectrometry, single crystal X-ray diffraction, and DFT studies.
Computed Properties of C13H10O. Welcome to talk about 119-61-9, If you have any questions, you can contact Adet, N; Specklin, D; Gourlaouen, C; Damiens, T; Jacques, B; Wehmschulte, RJ; Dagorne, S or send Email.
Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem