The three-dimensional configuration of the ester heterocycle is basically the same as that of the carbocycle. Compound: 1-Iodo-2-methylbutane(SMILESS: CCC(CI)C,cas:616-14-8) is researched.Safety of 1-Iodo-2-methylbutane. The article 《Preparation of (S)-2-methylbutyl and (S)-sec-butyl ketones from optically active 2-methyl-1-butanol by the dithiane method》 in relation to this compound, is published in Angewandte Chemie, International Edition in English. Let’s take a look at the latest research on this compound (cas:616-14-8).
Optically active aldehydes and ketones EtMeCHCRO (where R = H, Me, Ph, Me3Si, C5H11, or 1-cyclohexenyl) were prepared by treating EtMeCHCHO, obtained from EtMeCHCH2OH, with CH2(CH2SH)2 to give 2-(1-methylpropyl)-1,3-dithiane, which was then alkylated and hydrolyzed. The loss of optical activity was <20% for the reaction sequence. As far as I know, this compound(616-14-8)Computed Properties of C5H11I can be applied in many ways, which is helpful for the development of experiments. Therefore many people are doing relevant researches.
Reference:
Thiomorpholine – Wikipedia,
Thiomorpholine | C4H9NS – PubChem