In organic chemistry, atoms other than carbon and hydrogen are generally referred to as heteroatoms. The most common heteroatoms are nitrogen, oxygen and sulfur. Now I present to you an article called Long-chain syn-1-phenylalkane-1,3-diyl diacetates, related phenylalkane derivatives, and sec-alcohols, all possessing dominantly iso-branched chain termini, and 2/3-methyl-branched fatty acids from Primula veris L. (Primulaceae) wax, published in 2021-06-30, which mentions a compound: 616-14-8, mainly applied to Primula veris phenylalkane derivative secondary alc branched fatty acid; 1-Phenylalkane-1,3-diones; 2-Methylalkanoic and 3-methylalkanoic acids; 3-Oxo-1-phenylalkan-1-yl acetates; Branched long-chain wax constituents; Primula veris L.; Primulaceae; sec-Alcohols; syn-1-Phenylalkane-1,3-diyl diacetates, Recommanded Product: 616-14-8.
Herein, the results of the first study of non-flavonoid constituents of aboveground surface-wax washings of Primula veris L. (Primulaceae) are presented. Chromatog. of the washings yielded a minor fraction composed of n-, iso-, and anteiso-series of long-chained syn-1-phenylalkane-1,3-diyl diacetates, 3-oxo-1-phenylalkan-1-yl acetates, 1-phenylalkane-1,3-diones, 1-hydroxy-1-phenylalkan-3-ones, sec-alcs. (2- to 10-alkanols), and n-, iso-, anteiso-, 2-methylalkanoic and 3-methylalkanoic acids; 118 of these constituents represent up to now unreported natural compounds The structural/stereochem. elucidation was accomplished by the synthesis of authentic standards, derivatization reactions, the use of gas chromatog. retention data and detailed 1D and 2D-NMR analyses of the obtained complex chromatog. fraction. Primula veris produces unusually high amounts of branched long-chained metabolites (>60%) except for the fatty acids where the percentage of branched isomers is comparable to the ones with n-chains. Noteworthy is the fact that long-chained α- and β-Me substituted fatty acids were detected herein for the first time in the kingdom Plantae.
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Reference:
Thiomorpholine – Wikipedia,
Thiomorpholine | C4H9NS – PubChem