Colas, Kilian published the artcileIntermolecular Pummerer Coupling with Carbon Nucleophiles in Non-Electrophilic Media, Related Products of thiomorpholine, the main research area is intermol Pummerer coupling sulfoxide turbo organomagnesium amide; C−C coupling; Pummerer reaction; magnesium; main group elements; sulfur.
A new Pummerer-type C-C coupling protocol is introduced based on turbo-organomagnesium amides, which unlike traditional Pummerer reactions, does not require strong electrophilic activators, engages a broad range of C(sp3)-, C(sp2)-, and C(sp)-nucleophiles, and seamlessly integrates with C-H and C-X magnesiation. Given the central character of sulfur compounds in organic chem., this protocol allows access to unrelated carbonyls, olefins, organometallics, halides, and boronic esters through a single strategy.
Angewandte Chemie, International Edition published new progress about Grignard reagents. 220655-09-4 belongs to class thiomorpholine, name is tert-Butyl thiomorpholine-4-carboxylate, and the molecular formula is C9H17NO2S, Related Products of thiomorpholine.
Referemce:
Thiomorpholine – Wikipedia,
Thiomorpholine | C4H9NS – PubChem