Kamijo, Shin’s team published research in Angewandte Chemie, International Edition in 2016 | CAS: 220655-09-4

Angewandte Chemie, International Edition published new progress about C-H bond cleavage. 220655-09-4 belongs to class thiomorpholine, name is tert-Butyl thiomorpholine-4-carboxylate, and the molecular formula is C9H17NO2S, Name: tert-Butyl thiomorpholine-4-carboxylate.

Kamijo, Shin published the artcilePhoto-induced Substitutive Introduction of the Aldoxime Functional Group to Carbon Chains: A Formal Formylation of Non-Acidic C(sp3)-H Bonds, Name: tert-Butyl thiomorpholine-4-carboxylate, the main research area is formylation carbon hydrogen bond arylsulfonyl oxime; 4-benzoylpyridine; C−H functionalization; aldoximes; photoreactions; radicals.

A photo-induced substitutive introduction of an aldoxime functional group to carbon chains was achieved using photo-excited 4-benzoylpyridine as a C(sp3)-H bond cleaving agent and arylsulfonyl oxime as an aldoxime precursor. The non-acidic C-H bonds in various substances, including cycloalkanes, ethers, azacycles, and cyclic sulfides, were chemoselectively converted at ambient temperature under neutral conditions. The present transformation is a formal formylation of non-acidic C(sp3)-H bonds in a single step.

Angewandte Chemie, International Edition published new progress about C-H bond cleavage. 220655-09-4 belongs to class thiomorpholine, name is tert-Butyl thiomorpholine-4-carboxylate, and the molecular formula is C9H17NO2S, Name: tert-Butyl thiomorpholine-4-carboxylate.

Referemce:
Thiomorpholine – Wikipedia,
Thiomorpholine | C4H9NS – PubChem