One of the major reasons for studying chemical kinetics is to use measurements of the macroscopic properties of a system, COA of Formula: C4H9NO2S, such as the rate of change in the concentration of reactants or products with time.In a article, mentioned the application of 39093-93-1, Name is Thiomorpholine 1,1-dioxide, molecular formula is C4H9NO2S
Theoretical and experimental studies of cycloconjugation involving second-row elements
In a method proposed to investigate conjugative interactions between second-row elements (S, P) amd a pi-electron system, barriers to amide rotation have been measured using NMR line-shape methods, for N-acetyl-4-X(hetero)-1,4-dihydropyridines (X = SO2,7; P(O)OCH3,13; C(CH3)2, 6 (reference)) as well as the dihydro (8a) and tetrahydro (9) derivatives, respectively, of 7. It is suggested that such interactions would stabilize the transition states for amide rotation by cycloconjugation but not the planar equilibrium states, compressing the barriers relative to reference 6. In fact, amide barriers in 7,13, and N-acetylpyrrole are substantially (>6 kcal) less than in 6, 8ab, and 9, all ca. 17 kcal, in all of which saturated centers interrupt possible cycloconjugation. These conclusions are supported by the results of ab initio calculations at the Hartree-Fock level with the 3-21G(*) basis set.
One of the oldest and most widely used commercial enzyme inhibitors is aspirin, COA of Formula: C4H9NO2S, which selectively inhibits one of the enzymes involved in the synthesis of molecules that trigger inflammation. you can also check out more blogs about 39093-93-1
Reference£º
Thiomorpholine – Wikipedia,
Thiomorpholine | C4H9NS – PubChem