Synthetic Route of 1965-09-9, The transformation of simple hydrocarbons into more complex and valuable products via catalytic C¨CH bond functionalisation has revolutionised modern synthetic chemistry. 1965-09-9, Name is 4,4-Oxydiphenol, SMILES is OC1=CC=C(OC2=CC=C(O)C=C2)C=C1, belongs to thiomorpholine compound. In a article, author is Beller, M, introduce new discover of the category.
New cationic rhodium-amine complexes and their implication in the catalytic anti-Markovnikov oxidative amination of styrenes
The oxidative anti-Markovnikov amination of styrenes catalyzed by cationic rhodium complexes provides a new access to enamines. As catalyst precursors [Rh(cod)(amine)(2)](+) complexes have been identified and characterized for the first time by X-ray crystallography and NMR. While piperazine, N-methylpiperazine, and thiomorpholine form 1:1 Rh-amine complexes, nonchelating amines such as piperidine and diethylamine form 1:2 Rh-amine complexes. The easier dissociation of the amine ligand explains why monodentate amines give good yields of the corresponding enamines in contrast to bidentate amines. (C) 1998 Elsevier Science S.A. All rights reserved.
Synthetic Route of 1965-09-9, Consequently, the presence of a catalyst will permit a system to reach equilibrium more quickly, but it has no effect on the position of the equilibrium as reflected in the value of its equilibrium constant.I hope my blog about 1965-09-9 is helpful to your research.
Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem