As an important bridge between the micro and macro material world, chemistry is one of the main methods and means for humans to understand and transform the material world. In an article, author is Wei, Wen-Juan, once mentioned the application of 76-83-5, Name is (Chloromethanetriyl)tribenzene, molecular formula is C19H15Cl, molecular weight is 278.7754, MDL number is MFCD00000813, category is thiomorpholine. Now introduce a scientific discovery about this category, Formula: C19H15Cl.
Lead-free antimony-based halides bis(thiomorpholine) pentachloroantimonate(III) monohydrate
We have successfully synthesized a new antimony-based halide hydrate, bis(thiomorpholine) pentachloroantimonate(III) monohydrate (C4NSH10)(2)[SbCl5]center dot H2O (1, C4NSH10+ is thiomorpholine cation), which crystals in a centrosymmetric space group of Pbca. 1 features the R2MX5-type perovskite architecture and undergoes a first-order structural phase transition (PT) at 406.3 K, accompanying with prominent dielectric responses. The photoluminescence spectra reveal that 1 shows a broadband light emission and a long lifetime (2.77 mu s). In addition, the DFT calculation exhibits the organic thiomorpholine cation has a contribution to electronic band structures of 1, which is distinct with other halide bismuth (Bi) and antimony (Sb)-based hybrid perovskites. This finding opens up a potential pathway to construct new lead-free hybrid materials for application of the optoelectronics. (C) 2020 Elsevier B.V. All rights reserved.
Formula: C19H15Cl, The potential utility of systematic synthetic strategy will be applicable to efficient generations of chemical libraries of compounds to find hit molecules. I hope my blog about 76-83-5 is helpful to your research.
Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem