As an important bridge between the micro and macro material world, chemistry is one of the main methods and means for humans to understand and transform the material world. In an article, author is Jeon, Youngeun, once mentioned the application of 605-70-9, Name is Naphthalene-1,4-dicarboxylic acid, molecular formula is C12H8O4, molecular weight is 216.19, MDL number is MFCD00014312, category is thiomorpholine. Now introduce a scientific discovery about this category, Category: thiomorpholine.
Four copper(I) coordination polymers (CPs), {[CuIL]center dot CH3CN]}(n) (1), {[CuIL]center dot CHCl3}(n) (2), {[CuIL]center dot CH2Cl2}(n) (3), and [CuIL](n) (4), were prepared by self-assembly reactions between CuI and (2-pyrazinylcarbonyl)thiomorpholine (L). CPs 1-4 are interconnected by rhomboid Cu-I-2-Cu units. CPs 1 and 4 have one-dimensional loop-chain structures, and 2 and 3 adopt two-dimensional network structures. CPs 1-4 are pseudopolymorphic supramolecular isomers. CPs 2′ and 3′ are prepared by removal of solvate molecules from CPs 2 and 3, which are polymorphic supramolecular isomers with CP 4. Reversible crystal-to-crystal transformations were observed under appropriate conditions such as solvent or heat.
Future efforts will undeniably focus on the diversification of the new catalytic transformations. These may comprise an expansion of the substrate scope from aromatic and heteroaromatic compounds to other hydrocarbons. 605-70-9, you can contact me at any time and look forward to more communication. Category: thiomorpholine.
Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem