New Advances in Chemical Research, May 2021. The prevalence of solvent effects has motivated developing quantitative kinetic, and theoretical assessments of solvent structures and their interactions with reaction intermediates. In an article, author is Franek, W, once mentioned the application of 21145-77-7, Name is 1-(3,5,5,6,8,8-Hexamethyl-5,6,7,8-tetrahydronaphthalen-2-yl)ethanone, molecular formula is C18H26O, molecular weight is 258.4, MDL number is MFCD00437355, category is thiomorpholine. Now introduce a scientific discovery about this category, Safety of 1-(3,5,5,6,8,8-Hexamethyl-5,6,7,8-tetrahydronaphthalen-2-yl)ethanone.
In a new, feasible procedure five symmetrical para-substituted diaroylmethanes ((4-X-C6H4-CO)(2)-CH2; X = F, Cl, Br, CH3, and CH3O) are prepared, in most cases in very good yields. For purification and activation, they are converted into the copper(II) complexes of their enolates. Subsequently, three reaction steps with disulfur dichloride (S2Cl2), chlorine, and ethanethioic acid yield new CH-acidic dithio-bis-(diaroylmethanes), alpha-chlorosulfenic acid chlorides, and acetyl diaroylchloromethyl disulfides. The latter compounds are of interest for the liberation of highly reactive dithiirane/thiosulfine species. With thiomorpholine, alpha-chlorosulfenic acid chlorides give alpha-chlorosulfenic acid amides.
I am very proud of our efforts over the past few months and hope to 21145-77-7 help many people in the next few years. Safety of 1-(3,5,5,6,8,8-Hexamethyl-5,6,7,8-tetrahydronaphthalen-2-yl)ethanone.
Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem