An article Insight into the chemoselective aromatic vs. side-chain hydroxylation of alkylaromatics with H2O2 catalyzed by a non-heme imine-based iron complex WOS:000609012400013 published article about HYDROGEN-PEROXIDE; C-H; POLYAZADENTATE COMPLEXES; SELECTIVE HYDROXYLATION; IRON(IV)-OXO COMPLEXES; EFFICIENT CATALYSTS; BENZOIC-ACIDS; OXIDATION; BENZENE; PHENOL in [Ticconi, Barbara; Capocasa, Giorgio; Cerrato, Andrea; Di Stefano, Stefano; Lapi, Andrea; Marincioni, Beatrice; Lanzalunga, Osvaldo] Univ Roma La Sapienza, Dipartimento Chim, Ple A Moro 5, I-00185 Rome, Italy; [Ticconi, Barbara; Capocasa, Giorgio; Cerrato, Andrea; Di Stefano, Stefano; Lapi, Andrea; Marincioni, Beatrice; Lanzalunga, Osvaldo] Univ Roma La Sapienza, Dipartimento Chim, Sez Meccanismi Reaz, Ist CNR & Sistemi Biol ISB CNR, Ple A Moro 5, I-00185 Rome, Italy; [Olivo, Giorgio] Univ Girona, Inst Quim Computac & Catalisi IQCC, Campus Montilivi,C Maria Aurelia Capmany 69, Girona 17003, Spain; [Olivo, Giorgio] Univ Girona, Dept Quim, Campus Montilivi,C Maria Aurelia Capmany 69, Girona 17003, Spain; [Olivo, Giorgio] Univ Girona, Inst Quim Computac & Catalisi IQCC, Campus Montilivi, Girona 17071, Spain; [Olivo, Giorgio] Univ Girona, Dept Quim, Campus Montilivi, Girona 17071, Spain in 2021, Cited 75. The Name is Anthrone. Through research, I have a further understanding and discovery of 90-44-8. Recommanded Product: 90-44-8
The oxidation of a series of alkylaromatic compounds with H2O2 catalyzed by an imine-based non-heme iron complex prepared in situ by reaction of 2-picolylaldehyde, 2-picolylamine, and Fe(OTf)(2) in a 2 : 2 : 1 ratio leads to a marked chemoselectivity for aromatic ring hydroxylation over side-chain oxidation. This selectivity is herein investigated in detail. Side-chain/ring oxygenated product ratio was found to increase upon decreasing the bond dissociation energy (BDE) of the benzylic C-H bond in line with expectation. Evidence for competitive reactions leading either to aromatic hydroxylation via electrophilic aromatic substitution or side-chain oxidation via benzylic hydrogen atom abstraction, promoted by a metal-based oxidant, has been provided by kinetic isotope effect analysis.
About Anthrone, If you have any questions, you can contact Ticconi, B; Capocasa, G; Cerrato, A; Di Stefano, S; Lapi, A; Marincioni, B; Olivo, G; Lanzalunga, O or concate me.. Recommanded Product: 90-44-8
Reference:
Thiomorpholine – Wikipedia,
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