SDS of cas: 104-21-2. Recently I am researching about C-N BOND; SILVER-FREE; 2,3-DISUBSTITUTED BENZOFURANS; CATALYZED CYCLIZATION; GOLD CATALYSIS; COMPLEXES; ALKYNES; CARBOALKOXYLATION; CARBOTHIOLATION; REACTIVITY, Saw an article supported by the College of Science and Mathematics at California State University Fresno; ASIAgenzia Spaziale Italiana (ASI). Published in ROYAL SOC CHEMISTRY in CAMBRIDGE ,Authors: Le, Q; Dillon, CC; Lichtenstein, DA; Pisor, JW; Closser, KD; Muchalski, H. The CAS is 104-21-2. Through research, I have a further understanding and discovery of 4-Methoxybenzyl acetate
Homogeneous cationic gold(i) catalysis emerged as a preferred avenue for the activation of alkenes and alkynes towards reactions with weak nucleophiles, especially in cyclization reactions. Here we report an intramolecular carboalkoxylation reaction of electron-rich benzyl ethers of 2-ethynylaryl phenols catalysed by a digold(i)-NHC complex. The reaction proceeds efficiently with low catalyst loading and the resulting 2,3-disubstituted benzofurans form in moderate to good yields. Based on the results of a cross-over experiment, spectroscopic data, and DFT calculations, we propose a mechanism that accounts for the observed chemo- and regioselectivity.
About 4-Methoxybenzyl acetate, If you have any questions, you can contact Le, Q; Dillon, CC; Lichtenstein, DA; Pisor, JW; Closser, KD; Muchalski, H or concate me.. SDS of cas: 104-21-2
Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem