An article Exploring the copper binding ability of Mets7 hCtr-1 protein domain and His7 derivative: An insight in Michael addition catalysis WOS:000580957500001 published article about ARTIFICIAL METALLOENZYMES; ASYMMETRIC HYDROGENATION; PEPTIDES; COMPLEXES; 8-AMINO-5,6,7,8-TETRAHYDROQUINOLINE; KETONES in [Rimoldi, Isabella; Bucci, Raffaella; Feni, Lucia; Facchetti, Giorgio; Pellegrino, Sara] Univ Milan, Dipartimento Sci Farmaceut, Via Venezian 21, I-20133 Milan, Italy; [Santagostini, Laura] Univ Milan, Dipartimento Chim, Milan, Italy in 2021.0, Cited 48.0. The Name is 3-Nitrobenzaldehyde. Through research, I have a further understanding and discovery of 99-61-6. Quality Control of 3-Nitrobenzaldehyde
Mets7is a methionine-rich motif present in hCtr-1 transporter that is involved in copper cellular trafficking. Its ability to bind Cu(I) was recently exploited to develop metallopeptide catalysts for Henry condensation. Here, the catalytic activity ofMets7-Cu(I)complex in Michael addition reactions has been evaluated. Furthermore,His7peptide, in which Met residues have been substituted with His ones, was also prepared. This substitution allowedHis7to coordinate Cu (II), with the obtainment of a stable turn conformation as evicted by CD experiments.His7-Cu (II)proved also to be a better catalyst thanMets7-Cu(I)in the addition reaction. In particular, when the substrate was the (E)-1-phenyl-3-(pyridin-2-yl)prop-2-en-1-one, a conversion of 71% and a significative 58% of e.e. was observed.
Welcome to talk about 99-61-6, If you have any questions, you can contact Rimoldi, I; Bucci, R; Feni, L; Santagostini, L; Facchetti, G; Pellegrino, S or send Email.. Quality Control of 3-Nitrobenzaldehyde
Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem