In 2021.0 INORG CHEM published article about LITHIUM-MEDIATED ALUMINATION; CATALYTIC NITRENE TRANSFER; STRUCTURAL-CHARACTERIZATION; LACTIDE POLYMERIZATION; COORDINATION CHEMISTRY; CRYSTAL-STRUCTURES; AMIDE COMPLEXES; MAGNESIUM; LIGAND; METAL in [Gauld, Richard M.; Lynch, Jennifer R.; Kennedy, Alan R.; Mulvey, Robert E.] Univ Strathclyde, Dept Pure & Appl Chem, WestCHEM, Glasgow G1 1XL, Lanark, Scotland; [Barker, Jim; Reid, Jacqueline] Innospec Ltd, Ellesmere Port CH6S 4EY, Cheshire, England in 2021.0, Cited 67.0. The Name is Benzophenone. Through research, I have a further understanding and discovery of 119-61-9. Recommanded Product: Benzophenone
Homoleptic LiNacNac forms simple donor-acceptor complexes with N,N’-dicyclohexylcarbodiimide (CyN=C=NCy), triphenylphosphine oxide (Ph3P=O), and benzophenone (Ph2CO). These crystallographically characterized compounds could be regarded as model intermediates en route to reducing the N=C, P=O, and C=O bonds of unsaturated substrates. Heteroleptic NacNacMg(TMP) intriguingly functions as a TMP nucleophile both with t-BuNCO and t-BuNCS, producing a urea or thiourea derivative respectively attached to Mg, though the NacNac ligand in the former reaction also engages noninnocently with a second t-BuNCO molecule via insertion at the reactive NacNac backbone gamma-carbon site.
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Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem