I found the field of Chemistry very interesting. Saw the article Manganese-Catalyzed Hydrogenation of Ketones under Mild and Base-free Conditions published in 2021.0. Category: thiomorpholine, Reprint Addresses Kirchner, K (corresponding author), Vienna Univ Technol, Inst Appl Synthet Chem, A-1060 Vienna, Austria.. The CAS is 119-61-9. Through research, I have a further understanding and discovery of Benzophenone
In this paper, several Mn(I) complexes were applied as catalysts for the homogeneous hydrogenation of ketones. The most active precatalyst is the bench-stable alkyl bisphosphine Mn(I) complexfac-[Mn(dippe) (CO)(3)(CH2CH2CH3)]. The reaction proceeds at room temperature under base-free conditions with a catalyst loading of 3 mol % and a hydrogen pressure of 10 bar. A temperature-dependent selectivity for the reduction of alpha,beta-unsaturated carbonyls was observed. At room temperature, the carbonyl group was selectively hydrogenated, while the C=C bond stayed intact. At 60 degrees C, fully saturated systems were obtained. A plausible mechanism based on DFT calculations which involves an inner-sphere hydride transfer is proposed.
Category: thiomorpholine. Welcome to talk about 119-61-9, If you have any questions, you can contact Weber, S; Brunig, J; Veiros, LF; Kirchner, K or send Email.
Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem