Product Details of 99-61-6. Authors Li, Y; Liang, CM; Zou, XZ; Gu, JZ; Kirillova, MV; Kirillov, AM in MDPI published article about in [Li, Yu; Liang, Chumin; Zou, Xunzhong] Guangdong Ind Polytech, Foshan Res Ctr Special Funct Bldg Mat & Its Green, Guangdong Res Ctr Special Bldg Mat & Its Green Pr, Guangzhou 510300, Peoples R China; [Gu, Jinzhong] Lanzhou Univ, Coll Chem & Chem Engn, Lanzhou 730000, Peoples R China; [Kirillova, Marina V.; Kirillov, Alexander M.] Univ Lisbon, Inst Super Tecn, Ctr Quim Estrutural, Av Rovisco Pais, P-1049001 Lisbon, Portugal; [Kirillova, Marina V.; Kirillov, Alexander M.] Univ Lisbon, Inst Super Tecn, Dept Engn Quim, Av Rovisco Pais, P-1049001 Lisbon, Portugal; [Kirillov, Alexander M.] RUDN Univ, Peoples Friendship Univ Russia, Res Inst Chem, 6 Miklukho Maklaya St, Moscow 117198, Russia in 2021.0, Cited 44.0. The Name is 3-Nitrobenzaldehyde. Through research, I have a further understanding and discovery of 99-61-6
Three 2D coordination polymers, [Cu-2(mu(4)-dpa)(bipy)(2)(H2O)](n)center dot 6nH(2)O (1), [Mn-2(mu(6)-dpa)(bipy)(2)](n) (2), and [Zn-2(mu(4)-dpa)(bipy)(2)(H2O)(2)](n)center dot 2nH(2)O (3), were prepared by a hydrothermal method using metal(II) chloride salts, 3-(2 ‘,4 ‘-dicarboxylphenoxy)phthalic acid (H(4)dpa) as a linker, as well as 2,2 ‘-bipyridine (bipy) as a crystallization mediator. Compounds 1-3 were obtained as crystalline solids and fully characterized. The structures of 1-3 were established by single-crystal X-ray diffraction, revealing 2D metal-organic networks of sql, 3,6L66, and hcb topological types. Thermal stability and catalytic behavior of 1-3 were also studied. In particular, zinc(II) coordination polymer 3 functions as a highly active and recoverable heterogeneous catalyst in the mild cyanosilylation of benzaldehydes with trimethylsilyl cyanide to give cyanohydrin derivatives. The influence of various parameters was investigated, including a time of reaction, a loading of catalyst and its recycling, an effect of solvent type, and a substrate scope. As a result, up to 93% product yields were attained in a catalyst recoverable and reusable system when exploring 4-nitrobenzaldehyde as a model substrate. This study contributes to widening the types of multifunctional polycarboxylic acid linkers for the design of novel coordination polymers with notable applications in heterogeneous catalysis.
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Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem