Recently I am researching about SENSITIZED SOLAR-CELLS; ORGANIC-DYES; TRIPHENYLAMINE; DESIGN; DIPHENYLAMINE; ARYNES; FLUORESCENCE; ARYLATION; POLYMERS, Saw an article supported by the DST (New Delhi)Department of Science & Technology (India); DST (New Delhi)Department of Science & Technology (India) [SB/EMEQ-044/2014]. Published in ROYAL SOC CHEMISTRY in CAMBRIDGE ,Authors: Meerakrishna, RS; Shanmugam, P. The CAS is 88-68-6. Through research, I have a further understanding and discovery of 2-Aminobenzamide. SDS of cas: 88-68-6
Herein, via chemoselective N-mono and N,N-diarylation of an aryl/hetaryl amino amide reaction using benzyne or arynes, an amide-substituted triaryl amine derivative and diaryl amine derivatives were afforded. The scope and limitation of the present study have been studied. The products thus obtained were synthetically transformed to highly functionalized biphenyl bridged heterocycles via Suzuki coupling and condensation with 4,4-biphenyl dialdehyde. Evaluation of the photophysical properties has revealed that the triaryl amine derivatives are blue emissive with high quantum yields, whereas the heterocyclic triaryl amine derivatives are blue-red emissive. The benzofuran-derived compound 4i was found to be blue emissive with high quantum yield, whereas the pyridine-derived compound 5j was found to be red emissive with low quantum yield.
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Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem