Recommanded Product: 119-61-9. Authors Dmitrienko, A; Pilkington, M; Nikonov, GI in WILEY-V C H VERLAG GMBH published article about in [Dmitrienko, Anton; Pilkington, Melanie; Nikonov, Georgii I.] Brock Univ, Dept Chem, 1812 Sir Isaac Brock Way, St Catharines, ON L2S 3A1, Canada in 2021.0, Cited 22.0. The Name is Benzophenone. Through research, I have a further understanding and discovery of 119-61-9
The Al-I compound NacNacAl (1, NacNac = [ArNC(Me)CHC(Me)NAr](-), Ar = 2,6-iPr(2)C(6)H(3)) serves as a template for the chemoselective coupling between carbonyls (benzophenone, fenchone, isophorone, p-tolyl benzoate, N,N-dimethylbenzamide, (1-phenylethylidene)aniline) and pyridine. With the CH-acidic ketone (1R)-(+) camphor, the reaction affords a hydrido alkoxide compound of Al, formed as the result of enolization, whereas an enolizable imine, (1-phenylethylidene)aniline, and the bulky ketone isophorone, still chemoselectively couple with pyridine. In contrast, reaction with the ester p-tolyl benzoate results in cleavage of the ester bond together with replacement of the alkoxy group by a hydrogen atom of the pyridine moiety. This study demonstrates that for carbonyl substrates featuring phenyl substituents, the reaction proceeds via intermediate formation of eta(2)(C,X)-coordinated (X = O, N) carbonyl adducts, whereas the reaction of 1 with (R)-(-)-fenchone in the absence of pyridine leads to CH activation in the pendant isopropyl group of the Ar substituent of the NacNac ligand.
Welcome to talk about 119-61-9, If you have any questions, you can contact Dmitrienko, A; Pilkington, M; Nikonov, GI or send Email.. Recommanded Product: 119-61-9
Reference:
Thiomorpholine – Wikipedia,
,Thiomorpholine | C4H9NS – PubChem